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银掺杂介孔二氧化钛的制备及可见光催化性能

DOI: 10.7521/j.issn.0454-5648.2014.09.19

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Abstract:

以表面活性剂十六烷基三甲基溴化铵(CTAB)为模板、钛酸四丁酯为钛源、硝酸银为掺杂离子前驱体,通过液晶模板辅助溶胶-凝胶法制备银掺杂介孔二氧化钛(Ag/MT),借助于X射线衍射、N2吸附-脱附、差热分析仪、X射线光电子能谱、紫外可见分光光度计、透射电子显微镜等对样品的结构进行了表征,以亚甲基蓝(MB)为目标降解物,探讨了合成产物的可见光催化性能。结果表明银掺杂降低了介孔二氧化钛(MT)粒径和光生电子-空穴复合率,提高了比表面积和Ti3+和羟基浓度,使得Ag/MT的光催化活性高于纯MT和P25,银掺杂减小TiO2带隙能,使其具有很高的可见光催化活性。最佳光催化条件为Ag/MT和MB的浓度分别为0.6g/L和1mg/L。

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