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纳米CaF2对自润滑陶瓷材料力学性能的影响

DOI: 10.7521/j.issn.0454-5648.2014.09.08

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Abstract:

采用真空热压烧结工艺制备一种添加纳米固体润滑剂CaF2的新型自润滑陶瓷材料,其力学性能显著高于添加微米CaF2的自润滑陶瓷材料,并且断裂韧性高于不含CaF2的复合陶瓷材料。结果表明烧结后纳米CaF2主要位于基体晶粒内部,形成晶内型纳米结构。相比于添加微米CaF2,添加纳米CaF2时复合陶瓷材料的弹性模量增加了34%,这是材料硬度改善的主要原因。纳米CaF2诱发的穿晶断裂有助于提高复合陶瓷材料的断裂韧性和抗弯强度,裂纹偏转是添加纳米CaF2的复合陶瓷材料的主要增韧机制。

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