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锌掺杂对针状氧化铁的结构及电化学性能的影响

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Abstract:

采用微乳–超临界干燥法制备了Zn2+掺杂针状Zn0.34Fe2.66O4纳米晶。利用红外光谱仪、能谱仪、X射线衍射仪和透射电子显微镜对样品的晶体结构、化学组成、粒径和形貌进行表征。结果表明产物为形貌规整的针状,长径比明显小于Fe3O4的。通过循环伏安、恒流充放电和交流阻抗等方法研究了Zn0.34Fe2.66O4电极的电化学性能,结果表明在1mol/LH2SO4溶液中,在0~1.6V(vs饱和甘汞电极)电位范围内,Zn2+掺杂Zn0.34Fe2.66O4材料的电活性和循环稳定性、可逆性优于Fe3O4的。在1A/g电流密度下,单电极比容量达1116F/g,大电流充放电性能良好。

References

[1]  ? 谢文俊, 何雨石, 廖小珍, 等. 不同形貌Li4Ti5O12负极材料的研究进展[J]. 化工进展, 2011, 30(10) : 2220–2227.
[2]  XIE Wenjun, HE Yushi, LIAO Xiaozhen, et al. Chem Ind Eng Prog (in Chinese), 2011, 30(10): 2220–2227.
[3]  ? JI L W, TAN Z K, KUYKENDALL T R, et al. Fe3O4 nanoparticle - integrated grapheme sheets for high-performance half and full lithium ion cells [J]. Phys Chem, 2011, 13(15): 7170–7177.
[4]  ? MAHALAKSHMI S, MANJA K S. AC electrical conductivity and dielectric behavior of nanophase nickel ferrites [J]. J Alloy Compd, 2008, 457(1–2): 522–525.
[5]  ? MAZEN S A, TAHEI A M. The conduction mechanism of CuGe ferrite [J]. Solid State Commun, 2010, 150(35–36): 1719–1724.
[6]  ? 杨洪杰, 唐可, 徐光亮, 等. Ni–Ti复合取代锂铁氧体的显微结构及磁性能[J]. 硅酸盐学报, 2011, 39(12): 1963–1967.
[7]  YANG Hongjie, TANG Ke, XU Guangliang, et al. J Chin Ceram Soc, 2011, 39(12): 1963–1967.
[8]  ? JAIN G, BALASUBRAMANIAN M, XU J J. Structural studies of lithium intercalation in a nanocrystalline α-Fe2O3 compound [J].Chem Mater, 2006, 18(2): 423–434.
[9]  ? 李亚栋, 章建辉, 朱长飞. La0.67Sr0.33FexMn1–xO3制备和奇特磁电阻效应[J]. 物理化学学报, 1997, 13(12): 1079–1082.
[10]  LI Yadong, ZHANG Jianhui, ZHU Changfei. Acta Phys-Chim Sin (in Chinese), 1997, 13(12): 1079–1082.
[11]  ? ABDEEN A M. Electric conduction in Ni–Zn ferrites [J]. J Magn Magn Mater, 1998, 185(2): 199–206.
[12]  ? AHMED M A, ATEIA E, SALAH L M, et al. Effect of sintering conditions on the electrical properties of Ni1–xZnxLa0.05Fe1.95O4 [J]. phys Stat Sol (a), 2004, 201(13): 3010–3022.
[13]  ? MUHAMMAD N A, MUHAMMAD J I, IFTIKHAR H G. Effect of Al–Cr doping on the structural, magnetic and dielectric properties of strontium hexaferrite nanomaterials [J]. J Magn Magn Mater, 2011, 323(3–4): 259–263.
[14]  ? AHMED M A, ATEIA E, SALEM F M. Spectroscopic and electrical properties of Mg-Ti ferrite doped with different rare-earth elements [J]. Physica B, 2006, 381(1–2): 144–155.
[15]  ? PENG D L. Magnetic properties and magnetoresistance in small iron oxide cluster assemblies [J]. Appl Phys Lett, 2002, 81(24): 4598–4600.
[16]  ? PARK C, ZHU J G, PENG Y, et al. Inverse magnetoresistance in magnetic tunnel junction with an Fe3O4 electrode [J]. IEEE Trans Magn, 2005, 41(42): 2691–2693.
[17]  ? REISINGER D, MAJEWSKI P, OPEL M, et al. Hall effect, magnetization, and conductivity of Fe3O4 epitaxial thin films [J]. Appl Phys Lett, 2004, 85: 4980–4982.
[18]  ? AHMED M A, OKASHA N. Role of Cu2+ concentration on the structure and transport properties of Cr–Zn Ferrites [J]. J Magn Magn Mater, 2009, 321(20): 3436–3441.
[19]  ? 蒋荣立, 张宗祥, 孙强, 等. 钕离子掺杂铁氧体纳米晶的结构和磁性能[J]. 硅酸盐学报, 2008, 12(7): 41–46.
[20]  JIANG Rongli, ZHANG Zongxiang, SHUN Qiang, et al. J Chin Ceram Soc, 2008, 12(7): 41–46.
[21]  ? 颜爱国, 刘浩梅, 刘聘婷, 等. Fe3O4和Zn2+掺杂型Zn1–xFe2+xO4纳米晶的溶剂热合成和电磁性能[J]. 高等学校化学学报, 2010, 3(3): 441–451.
[22]  YAN Aiguo, LIU Haomei, LIU Pinting, et al. Chem J Chin Univ (in Chinese), 2010, 3(3): 441–451.
[23]  ? 陈洁, 黄可龙, 刘素琴. 球形纳米Fe3O4的制备及超级电容性能研究[J]. 无机化学学报, 2008, 124(4): 621–626.
[24]  CHEN Jie, HUANG Kelong, LIU Suqin. Chin J Inorg Chem (in Chinese), 2008, 124(4): 621–626.
[25]  ? 曾雯雯, 黄可龙, 杨幼平, 等. 溶剂热法合成不同形貌的Co3O4及其电容特性[J]. 物理化学学报, 2008, 24(2): 263–268.
[26]  ZENG Wenwen, HUANG Kelong, YANG Youping, et al. Acta Phys-Chim Sin (in Chinese), 2008, 24(2): 263–268.
[27]  ? WANG F B, CHEN J, HUANG K L, et al. Preparation and electrochemical performance of spherical Fe3O4 as anode materials for Li-ion batteries [J]. Sci China Ser E, 2009, 52(11): 3219–3223.
[28]  

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