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电解质支撑电池的NiO-Ce0.9Gd0.1O1.95阳极的制备及性能

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Abstract:

采用流延法制备电解质支撑基片,结合丝网印刷电极制备了结构为NiO-GDC/8YSZ/LSM-SSZ的电解质支撑平板型单电池。NiO-GDC阳极烧结温度分别为1100、1150、1200、1250和1300℃,而LSM-SSZ阴极烧结温度固定为1100℃。对制备的电池样品分别进行了直流放电电流–电压(I–V)、交流阻抗(EIS)及扫描电镜(SEM)测试。I–V曲线显示,阳极烧温分别为1100、1150、1200、1250和1300℃的电池800℃测试所得最大功率密度分别为540、529、648、715和359mW/cm2。阳极1250℃烧结电池样品800℃下测试的最大功率密度值最优为715mW/cm2,极化电阻最小为0.276??cm2。阳极烧结温度对电池阳极的微结构及电性能影响显著,通过控制阳极烧结温度可得到优异的电池结构与性能。

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