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环境化学  2015 

气溶胶水溶性有机物(WSOC)中二元羧酸的测定

Keywords: 气溶胶,水溶性有机物,乙二酸,丙二酸,丁二酸

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Abstract:

提出了BF3/丁醇酯化衍生反应GC/MS分析大气气溶胶水溶性有机物(WSOC)中二元羧酸(乙二酸、丙二酸和丁二酸)的测定方法.其相应酯化产物乙二酸二丁酯、丙二酸二丁酯和丁二酸二丁酯的线性范围为1×10-5mol·l-1—1×10-2mol·l-1,精密度分别为1.67%,3.04%和5.28%;最低检测限分别为1.9×10-7mol·l-1,1.1×10-7mol·l-1和1.25×10-6mol·l-1.并实测了北京市秋、冬两季乙二酸、丙二酸和丁二酸的平均浓度水平,分别为444ng·m-3,40ng·m-3,302ng·m-3.

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