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环境化学  2015 

羰基硫(COS)在土壤中的吸收与转化

Keywords: 羰基硫(COS),土壤,水溶性硫酸盐

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Abstract:

利用静态法研究了羰基硫(COS)在草坪土壤中的吸收与转化过程.土壤对COS的吸收速率与土壤的含水量和温度呈非线性关系,土壤吸收COS的最适宜温度为25℃,含水量为13%.在此条件下,大气COS的估算交换通量为1.84pmol·g-1(DW)·h-1或5.98pmol·m-2·s-1.采用GCFID,FPD和IC对土壤吸收COS可能的转化产物进行了测定,结果表明,CO2和SO42-为主要反应产物,其中约50%的COS最终转化为水溶性硫酸盐,约50%的COS可能转化为其它非挥发性含硫化合物(可能主要为FeS).

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