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环境化学  2015 

烯烃气相臭氧化反应机理的研究进展

Keywords: 烯烃,气相臭氧化,Criegee中间体,·OH自由基,二次有机气溶胶

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Abstract:

气相条件下的烯烃臭氧化反应是大气中极其重要的反应之一,是多种自由基以及二次有机气溶胶的重要来源,与大气环境和人类生活密切相关.综合以往的研究成果,对早期提出的Criegee机理做了简介,着重阐述了Criegee中间体(CI)的结构及其相关反应、羟自由基的形成机理及萜烯臭氧化形成二次有机气溶胶产物的机理.最后,对未来的研究方向进行了探讨.

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