全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
化工进展  2015 

二氧化碳的活化及其催化加氢制二甲醚的研究进展

DOI: 10.16085/j.issn.1000-6613.2015.01.021, PP. 119-126

Keywords: 二氧化碳,加氢,动力学模型,催化,多相反应

Full-Text   Cite this paper   Add to My Lib

Abstract:

CO2是一种稳定的物质,其化学惰性限制了CO2转化技术的发展。本文介绍了化学催化、生物活化、光电活化及等离子体活化等CO2活化方式,从CO2催化加氢合成二甲醚的工艺研究、催化剂开发、催化加氢机理和本征动力学研究等方面综述了CO2催化加氢合成二甲醚的研究进展,认为化学催化法是目前应用最广泛的一种CO2活化方式。对于一步法催化CO2加氢合成二甲醚的工艺,其难点是制备高效CO2活化催化剂。开发高效的CO2活化及转化催化剂及对CO2合成二甲醚的反应过程进行机理探究,是推广CO2转化技术的关键。

References

[1]  程伟,程晓晶,王雪枫. 直馏汽油异构催化剂的研究进展[J]. 化工进展,2013,32(2):333-339.
[2]  Wang W,Wang S-P,Ma X-B,et al. Recent advances in catalytic hydrogenation of carbon dioxide[J]. Chemical Society Reviews,2011,40(7):3703-3727.
[3]  Grzybek T,Klinik J,Samojeden B,et al. Nitrogen-promoted active carbons as DeNOx catalysts 1. The influence of modification parameters on the structure and catalytic properties[J]. Catalysis Today,2008,137:228-234.
[4]  Weyda H,K?hler E. Modern refining concepts-an update on naphtha-isomerization to modern gasoline manufacture[J]. Catalysis Today,2003,81(1):51-55.
[5]  朱云霞. 加速发展C5/C6正构烷烃异构化工艺[J]. 炼油技术与工程,2004,33(8):1-4.
[6]  郑冬梅. C5/C6烷烃异构化生产工艺及进展[J]. 石油化工设计,2005,21(3):1-5.
[7]  Lu W-Z,Teng L-H,Xiao W-D. Simulation and experiment study of dimethyl ether synthesis from syngas in a fluidized-bed reactor[J]. Chemical Engineering Science,2004,59(22-23):5455-5464.
[8]  Grzybek T,Klinik J,Samojeden B,et al. Nitrogen-promoted active carbons as DeNOx catalysts 2. The influence of Mn promotion on the structure and catalytic properties in SCR [J]. Catalysis Today,2008,137:235-241.
[9]  Busca G,Lorenzelli V,Sanchez Escribano V. Preparation,solid-state characterization,and surface chemistry of high-surface-area nickel-aluminum (NixAl2-2xO3-2x) mixed oxides[J]. Chemistry of Materials,1992,4(3):595-605.
[10]  Yang Y-X,Evans J,Rodriguez J A,et al. Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111),Cu clusters,and Cu/ZnO (000 )[J]. Physical Chemistry Chemical Physics,2010,12(33):9909-9917.
[11]  陶旭梅,孙晋良,柳文杰,等. CO2和H2合成甲醇的量子化学模拟[J]. 天然气化工:C1化学与化工,2013,38(3):57-61.
[12]  胡建水,王程俊,刘雷,等. 完全液相法催化剂上甲醇脱水合成二甲醚的动力学及DFT研究[J]. 化工学报,2012,63(3):819-825. 浏览
[13]  Wang W H,Huang B C,Wang L S. Oxidative treatment of multi-wall carbon nanotubes with oxygen dielectric barrier discharge plasma[J]. Surface & Coatings Technology,2011,205:4896-4901.
[14]  周红军. 催化裂化原料油加氢脱金属催化剂研究[D]. 青岛:中国石油大学化学工程与技术学院,2011.
[15]  Busca,G,Lorenzelli,V,Escribano Sanchez V,et al. FT-IR study of the surface properties of the spinels NiAl2O4 and CoAl2O4 in relation to those of transitional aluminas[J]. J. Catal.,1991,131,167-177.
[16]  Shim H M,Lee S J,Yoo Y D,et al. Simulation of DME synthesis from coal syngas by kinetics model[J]. Korean Journal of Chemical Engineering,2009,26(3):641-648.
[17]  Ayame A,Sawada G,Sato H,et al. Characterization of chlorine- treated alumina surfaces[J]. Applied Catalysis,1989,48(1):25-35.
[18]  An X,Zuo Y-Z,Zhang Q,et al. Dimethyl ether synthesis from CO2 hydrogenation on a CuO-ZnO-Al2O3-ZrO2/HZSM-5 bifunctional catalyst[J]. Industrial & Engineering Chemistry Research,2008,47(17):6547-6554.
[19]  Baumgarten E,Zachos A. Spectroscopic investigations of halogenated aluminas and silica aluminas[J]. Spectrochimica Acta Part A:Molecular Spectroscopy,1981,37(9):757-761.

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133