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化工进展  2015 

软质聚氨酯泡沫塑料无卤阻燃技术研究进展

DOI: 10.16085/j.issn.1000-6613.2015.09.022

Keywords: 复合材料,聚合物,制备,软质聚氨酯泡沫,阻燃

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Abstract:

软质聚氨酯泡沫(FPUF)是聚氨酯材料的主要产品之一,由于其较低的密度和热传导率而易燃,在燃烧过程中会放出大量烟雾和有毒气体,对FPUF进行阻燃处理尤为重要。卤系阻燃剂由于存在潜在的毒性和环境问题而受到限制,因此FPUF的无卤阻燃技术是今后主要的研究方向。本文综述了近年有关软质聚氨酯泡沫无卤阻燃技术的研究进展,包括添加型无卤阻燃剂法、反应型无卤阻燃剂法、层层组装涂层法。指出开发高相对分子质量、含多种阻燃元素的有机添加型阻燃剂和膨胀型阻燃剂以及复配型阻燃剂,解决层层组装涂层法的组装慢等问题将是FPUF无卤阻燃技术的发展趋势。

References

[1]  Fang M L,Webster T F,Gooden D,et al. Investigating a novel flame retardant known as V6:Measurements in baby products,house dust,and car dust[J]. Environ. Sci. Technol.,2013,47(9):4449-4454.
[2]  Singh H,Jain A K. Ignition,combustion,toxicity,and fire retardancy of polyurethane foams:A comprehensive review[J]. J. Appl. Polym. Sci.,2008,111(2):1115-1143.
[3]  张晓光,王列平,宁斌科,等. 聚氨酯泡沫塑料无卤阻燃技术的研究进展[J]. 化工进展,2012,31(7):1521-1526.
[4]  Liang S Y,Neisius N M,Gaan S. Recent developments in flame retardant polymeric coatings[J]. Prog. Org. Coat.,2013,76(11):1642-1665.
[5]  Levchik S V,Weil E D. A review of recent progress in phosphorus-based flame retardants[J]. J. Fire Sci.,2006,24(5):345-364.
[6]  K?nig A,Kroke E. Methyl-DOPO-a new flame retardant for flexible polyurethane foam[J]. Polym. Advan. Technol.,2011,22(1):5-13.
[7]  K?nig A,Kroke E. Flame retardancy working mechanism of methyl-DOPO and MPPP in flexible polyurethane foam[J]. Fire Mater.,2012,36(1):1-15.
[8]  Liang S Y,Neisius M,Mispreuve H,et al. Flame retardancy and thermal decomposition of flexible polyurethane foams:Structural influence of organophosphorus compounds[J]. Polym. Degrad. Stabil.,2012,97(11):2428-2440.
[9]  Stowell J,Liu W H. Phosphate ester flame retardant and resins containing same:US,20100137465[P]. 2010-06-03.
[10]  Stowell J,Pirrelli R,Dashevsky S. Polyurethane foam composition containing flame-retardant,and process for making same,flame retardant composition and polyurethane foam made therefrom:EP,2393874[P]. 2011-12-14.
[11]  Block M B,Ferbitz J,Henze O S,et al. Derivatives of diphosphines as flame retardants for polyurethanes:US,20110190407[P]. 2011-08-04.
[12]  Piotrowski A M,Dashevsky S,Levchik S,et al. Flame-retardant flexible polyurethane foam:US,8058322[P]. 2011-11-15.
[13]  Kim Y S,Davis R,Cain A A,et al. Development of layer-by-layer assembled carbon nanofiber-filled coatings to reduce polyurethane foam flammability[J]. Polymer,2011,52(13):2847-2855.
[14]  Laufer G,Kirkland C,Cain A A,et al. Clay-chitosan nanobrick walls:Completely renewable gas barrier and flame-retardant nanocoatings[J]. ACS Appl. Mater. Interfaces,2012,4(3):1643-1649.
[15]  Kim Y S,Harris R,Davis R. Innovative approach to rapid growth of highly clay-filled coatings on porous polyurethane foam[J]. ACS Macro Lett.,2012,1(7):820-824.
[16]  Li Y C,Kim Y S,Shields J,et al. Controlling polyurethane foam flammability and mechanical behaviour by tailoring the composition of clay-based multilayer nanocoatings[J]. J. Mater. Chem. A,2013,1(41):12987.
[17]  Kim Y S,Li Y C,Pitts W M,et al. Rapid growing clay coatings to reduce the fire threat of furniture[J]. ACS Appl. Mater. Interfaces,2014,6(3):2146-2152.
[18]  Cain A A,Nolen C R,Li Y C,et al. Phosphorous-filled nanobrick wall multilayer thin film eliminates polyurethane melt dripping and reduces heat release associated with fire[J]. Polym. Degrad. Stabil.,2013,98(12):2645-2652.
[19]  Kim Y S,Davis R. Multi-walled carbon nanotube layer-by-layer coatings with a trilayer structure to reduce foam flammability[J]. Thin Solid Films,2014,550(1):184-189.
[20]  Pan H F,Pan Y,Wang W,et al. Synergistic effect of layer-by-layer assembled thin films based on clay and carbon nanotubes to reduce the flammability of flexible polyurethane foam[J]. Ind. Eng. Chem. Res.,2014,53(37):14315-14321.
[21]  Laufer G,Kirkland C,Morgan A B,et al. Exceptionally flame retardant sulfur-based multilayer nanocoating for polyurethane prepared from aqueous polyelectrolyte solutions[J]. ACS Macro Lett.,2013,2(5):361-365.
[22]  Thirumal M,Singha N K,Khastgir D,et al. Halogen-free flame-retardant rigid polyurethane foams:Effect of alumina trihydrate and triphenylphosphate on the properties of polyurethane foams[J]. J. Appl. Polym. Sci.,2010,116(4):2260-2268.
[23]  K?nig A,Malek A,Fehrenbacher U,et al. Silane-functionalized flame-retardant aluminum trihydroxide in flexible polyurethane foam[J]. J. Cell. Plast.,2010,46(5):395-413.
[24]  Lorenzetti A,Modesti M,Besco S,et al. Influence of phosphorus valency on thermal behaviour of flame retarded polyurethane foams[J]. Polym. Degrad. Stabil.,2011,96(8):1455-1461.
[25]  Allan D,Daly J H,Liggat J J. Thermal volatilisation analysis of a TDI-based flexible polyurethane foam containing ammonium polyphosphate[J]. Polym. Degrad. Stabil.,2014,102:170-179.
[26]  欧育湘,李建军. 阻燃剂--性能、制造及应用[M]. 北京:化学工业出版社,2006.
[27]  Wu D,Zhao P,Liu Y. Flame retardant property of novel intumescent flame retardant rigid polyurethane foams[J]. Polym. Eng. Sci.,2013,53(11):2478-2485.
[28]  Xu Z Z,Huang J Q,Chen M J,et al. Flame retardant mechanism of an efficient flame-retardant polymeric synergist with ammonium polyphosphate for polypropylene[J]. Polym. Degrad. Stabil.,2013,98(10):2011-2020.
[29]  Chen M J,Shao Z B,Wang X L,et al. Halogen-free flame-retardant flexible polyurethane foam with a novel nitrogen-phosphorus flame retardant[J]. Ind. Eng. Chem. Res.,2012,51(29):9769-9776.
[30]  Chen M J,Xu Y J,Rao W H,et al. Influence of valence and structure of phosphorus-containing melamine salts on the decomposition and fire behaviors of flexible polyurethane foams[J]. Ind. Eng. Chem. Res.,2014,53(21):8773-8783.
[31]  Modesti M,Lorenzetti A,Simioni F,et al. Expandable graphite as an intumescent flame retardant in polyisocyanurate-polyurethane foams[J]. Polym. Degrad. Stabil.,2002,77(2):195-202.
[32]  Bashirzadeh R,Gharehbaghi A. An investigation on reactivity,mechanical and fire properties of Pu flexible foam[J]. J. Cell. Plast.,2010,46(2):129-158.
[33]  王成群,张佳丹,吕海宁,等. 可膨胀石墨阻燃高回弹聚氨酯泡沫塑料的性能[J]. 功能高分子学报,2011,24(2):204-210.
[34]  Bourbigot S,Samyn F,Turf T,et al. Nanomorphology and reaction to fire of polyurethane and polyamide nanocomposites containing flame retardants[J]. Polym. Degrad. Stabil.,2010,95(3):320-326.
[35]  Qian L,Feng F,Tang S. Bi-phase flame-retardant effect of hexa-phenoxy-cyclotriphosphazene on rigid polyurethane foams containing expandable graphite[J]. Polymer,2014,55(1):95-101.
[36]  Wolska A,Go?dzikiewicz M,Ryszkowska J. Thermal and mechanical behaviour of flexible polyurethane foams modified with graphite and phosphorous fillers[J]. J. Mater. Sci.,2012,47(15):5627-5634.
[37]  Wolska A,Go?dzikiewicz M,Ryszkowska J. Influence of graphite and wood-based fillers on the flammability of flexible polyurethane foams[J]. J. Mater. Sci.,2012,47(15):5693-5700.
[38]  Wang C Q,Ge F Y,Sun J,et al. Effects of expandable graphite and dimethyl methylphosphonate on mechanical,thermal,and flame-retardant properties of flexible polyurethane foams[J]. J. Appl. Polym. Sci.,2013,130(2):916-926.
[39]  赵义平,阎家建,陈丁猛,等. 复配无卤阻燃聚氨酯泡沫塑料的制备与表征[J]. 功能材料,2013,44(5):697-699.
[40]  Mack A G,Tsao T. Mixed glycol polyphosphonate compouonds:US,20110218260[P]. 2011-09-08.
[41]  Block M B,Ferbitz J,Fleckenstein C,et al. Polymeric flame retardant:US,20120010312[P]. 2012-01-12.
[42]  Qi Y D,Tai X Y. Phosphorous-containing flame retardants for polyurethane foams:EP,2688953[P]. 2014-08-27.
[43]  Piotrowski A,Desikan A N,Dashevsky S. Monohydroxy cyclic phosphonate substantially free of polyhydoxy phosphonate,process for making same and flame retardant flexible polyurethane foam obtained therefrom:EP,2619213[P]. 2014-09-03.
[44]  Chen M J,Chen C R,Tan Y,et al. Inherently flame-retardant flexible polyurethane foam with low content of phosphorus-containing cross-linking agent[J]. Ind. Eng. Chem. Res.,2014,53(3):1160-1171.
[45]  Bruchmann B,Schonfelder D,Ferbitz J,et al. Process for producing flame-retardant Pu foams:US,20110257284[P]. 2011-10-20.
[46]  Wiebke M,Mathias D,Martin S. Mixtures of phosphorus-containing compounds,method for production of the same and use of the same as flame-retardant material:EP,2062905[P]. 2012-01-11.
[47]  Nazaré S,Davis R D. A review of fire blocking technologies for soft furnishings[J]. Fire Science Reviews,2012,1(1):1-23.
[48]  Alongi J,Carosio F,Frache A,et al. Layer by Layer coatings assembled through dipping,vertical or horizontal spray for cotton flame retardancy[J]. Carbohyd. Polym.,2013,92(1):114-119.
[49]  Li Y C,Schulz J,Grunlan J C. Polyelectrolyte/nanosilicate thin-film assemblies:Influence of pH on growth,mechanical behavior,and flammability[J]. ACS Appl. Mater. Interfaces,2009,1(10):2338-2347.
[50]  Engels H W,Pirkl H G,Albers R,et al. Polyurethanes:Versatile materials and sustainable problem solvers for today's challenges[J]. Angew. Chem. Int. Ed.,2013,52(36):9422-9441.
[51]  Levchik S V,Weil E D. Thermal decomposition,combustion and fire-retardancy of polyurethanes-A review of the recent literature[J]. Polym. Int.,2004,53(11):1585-1610.
[52]  Valencia L B,Rogaume T,Guillaume E,et al. Analysis of principal gas products during combustion of polyether polyurethane foam at different irradiance levels[J]. Fire Safety J.,2009,44(7):933-940.
[53]  Denecker C,Liggat J J,Snape C E. Relationship between the thermal degradation chemistry and flammability of commercial flexible polyurethane foams[J]. J. Appl. Polym. Sci.,2006,100(4):3024-3033.
[54]  Tokuyasu N,Fujimoto K,Hirata M. Organophosphorus compound having phosphate-phosphonate bond,and flame-retardant polyester fiber and flame-retardant polyurethane resin composition each containing the same:EP,1632497[P]. 2012-04-18.
[55]  Dasari A,Yu Z Z,Cai G P,et al. Recent developments in the fire retardancy of polymeric materials[J]. Prog. Polym. Sci.,2013,38(9):1357-1387.
[56]  K?nig A,Fehrenbacher U,Hirth T,et al. Flexible polyurethane foam with the flame-retardant melamine[J]. J. Cell. Plast.,2008,44(6):469-480.
[57]  K?nig A,Fehrenbacher U,Kroke E,et al. Thermal decomposition behavior of the flame retardant melamine in slabstock flexible polyurethane foams[J]. J. Fire Sci.,2009,27(3):187-211.
[58]  Gharehbaghi A,Bashirzadeh R,Ahmadi Z. Polyurethane flexible foam fire resisting by melamine and expandable graphite:Industrial approach[J]. J. Cell. Plast.,2011,47(6):549-565.
[59]  Wang C Q,Lv H N,Sun J,et al. Flame retardant and thermal decomposition properties of flexible polyurethane foams filled with several halogen-free flame retardants[J]. Polym. Eng. Sci.,2014,54(11):2497-2507.
[60]  张宏,蔡哲,张翔宇,等. 有机协效阻燃剂的研究与应用[J]. 材料导报,2011,25(17):457-463.
[61]  Neisius M,Liang S Y,Mispreuve H,et al. Phosphoramidate-containing flame-retardant flexible polyurethane foams[J]. Ind. Eng. Chem. Res.,2013,52(29):9752-9762.
[62]  Stowell J,Liu W H. Phosphoramide ester flame retardant and resins containing same:US,20100063169[P]. 2010-03-11.
[63]  Nascher R,Gaan S,Neisius M,et al. Novel phosphonamidates-synthesis and flame retardant applications:EP,2557085[P]. 2013-02-13.
[64]  彭华乔,陈业中,刘又瑞,等. 含磷氮硫阻燃剂阻燃软质聚氨酯泡沫的研究[J]. 化工新型材料,2014,42(3):176-178.
[65]  K?bisch B,Fehrenbacher U,Kroke E. Hexamethoxycyclotriphosphazene as a flame retardant for polyurethane foams[J]. Fire Mater.,2014,38(4):462-473.
[66]  汪关才,卢忠远,胡小平,等. 无机阻燃剂的作用机理及研究现状[J]. 材料导报,2007,21(2):47-50.

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