|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
氨基硅烷外给电子体用于1-丁烯聚合的研究
DOI: 10.3724/SP.J.1105.2011.10367, PP. 1412-1418
Keywords: Ziegler-Natta催化剂,外给电子体,氨基硅烷类化合物,聚(1-丁烯)
Abstract:
合成了4种氨基硅烷类外给电子体,并用于MgCl2载体型Ziegler-Natta催化剂催化1-丁烯聚合,研究了不同外给电子体结构对催化效率和聚合物等规度、熔点、分子量及其分布的影响.结果表明,含二甲氧基的氨基硅烷类外给电子体更有助于聚(1-丁烯)等规度的提高,含二乙氧基的氨基硅烷类外给电子体可以使聚(1-丁烯)分子量分布变宽.此外,还研究了二哌啶基二甲氧基硅烷、原硅酸乙酯两种外给电子体复配对聚合的影响.研究发现,这两种外给电子体复配可以使聚合活性和聚合物等规度增加、聚合物分子量分布变宽.同时,氢气的加入量,不同的助催化剂及其加入量对以二哌啶基二甲氧基硅烷为外给电子体的聚合体系的活性和聚合物结构都有一定的影响.
| [1] | 4 Bi Fuyong(毕福勇),Zhang Hexia(张合霞),Zhao Yongxian(赵永仙),Wang Deqian(王德乾),Yao Wei(姚薇),Huang Baochen(黄宝琛).China Elastomerics(弹性体),2007,17(1): 40~44
|
| [2] | 5 Ren Hegang(任合刚),Wang Xi(王曦),Wang Luhai(王路海),Zhang Ningning(张宁宁),LiuPange(刘盘阁),Ji Rongqin(姬荣琴),Yan Weidong(闫卫东).Polymer Materials Science & Engineering(高分子材料科学与工程),2009,25(3):13~16
|
| [3] | 7 Abedi S,Sharifi-Sanjani N.J Appl Polym Sci,2000,78(14): 2533~2539
|
| [4] | 10 Chen Kewen(陈克文),Xu Kezhong(徐可忠),Ren Hegang(任合刚),Wang Yali(王亚丽),Yang Min(杨敏),Yan Weidong(闫卫东),Liu Binyuan(刘宾元).Speciality Petrochemicals(精细石油化工),2010,27(5): 9~12
|
| [5] | 12 Wen Xiaojing(温笑菁),Ji Mian(冀棉),Lu Li(逯丽),Niu Hui(牛慧),Dong Jinyong(董金勇).Polymer Bulletin(高分子通报),2010,(6): 53~60
|
| [6] | 13 Gao M Z,Liu H T,Wang J,Li C X,Ma J,Wei G S.Polymer,2004,45: 2175~2180
|
| [7] | 15 Duranel L,Spitz R,Soto T.Fra Pat,US patent,5192732.1993-03-09
|
| [8] | 18 Miro N D,Georgellis G B,Sewi H.Tex Pat,US patent,6111039.2000-08-29
|
| [9] | 19 Cui Nannan(崔楠楠),Zhang Zhicheng(张志成),Li Huayi(李化毅),Chen Shangtao(陈商涛),Zhang Xiaofan(张晓帆),Ke Yucai(柯毓才),Hu Youliang(胡友良).Acta Polymerica Sinica(高分子学报),2005,(6): 902~906
|
| [10] | 20 Lei Hua(雷华),Xu Hongbin(徐宏彬),Feng Lianfang(冯连芳),Yang Aiwu(杨爱武),WengZhixue(翁志学),Xu Guobin(徐国斌).Petrochemical Technology(石油化工),2003,13(12): 1087~1090
|
| [11] | 1 Luciani L,Sepp？l？ J, Lfgren B.Prog Polym Sci,1988,13(1): 37~62
|
| [12] | 2 Liu Juntao(刘俊涛),Zhong Siqing(钟思青),Xu Chunming(徐春明),Xie Zaiku(谢在库),Yang Weimin(杨为民).Petrochemical Technology(石油化工),2005,34(1): 9~13
|
| [13] | 3 Liu Xiaohan(刘晓晗),Liu Chenguang(刘晨光),Zhao Zhichao(赵志超),Huang Baochen(黄宝琛).China Synthetic Rubber Industry(合成橡胶工业),2010,33(1): 71~76
|
| [14] | 6 Sheng Haibo(盛海波),Wang Bo(王波),Yao Wei(姚薇),Zhao Yongxian(赵永仙),Li Xudong(李旭东),Huang Baochen(黄宝琛).China Elastomerics(弹性体),2005,15(3): 21~23
|
| [15] | 8 Kashiwa N,Yoshitake J,Mizuno A,Tsutsui T.Polymer,1987,28(6): 1227~1231
|
| [16] | 9 Xu Chunsheng(许春生),Shao Huafeng(邵华锋),Yao Wei(姚薇),Huang Baochen(黄宝琛).China Elastomerics(弹性体),2009,19(4): 6~8
|
| [17] | 11 Ikeuchi H,Yano T,Ikai S,Sato H,Yamashita J.J Mole Catal A: Chem,2003,193: 207~215
|
| [18] | 14 Yuan Chunhai(袁春海),Li Huayi(李化毅),Hu Youliang(胡友良).Polymer Bulletin(高分子通报),2009,(10): 38~42
|
| [19] | 16 Ishimaru N,Kioka M,Toyota A.Jpn Pat,US patent,5652303.1997-07-29
|
| [20] | 17 Cai Shijin(蔡世锦),Lu Honglan(陆宏兰),Zhang Jun(张军),Xiao Shijing(肖士镜).Acta Polymerica Sinica(高分子学报),1993,(6): 733~736
|
| [21] | 21 Noristi L,Barbe P C,Baruzzi G.Macromol Chem,1991,192(5):1115~1127
|
| [22] | 22 Potapov A G,Bukatov G D,Zakharov V A.J Mole Catal A: Chem,2010,316: 95~99
|
| [23] | 23 Sergeev S A,Bukatov G D,Zakharov V A.Macromol Chem,1984,185(11): 2377~2385
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
