|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
发近红外光的高分子铒络合物的合成及性能研究
DOI: 10.3724/SP.J.1105.2012.12023, PP. 1289-1294
Keywords: 铒离子,8-羟基喹啉,N-乙烯基咔唑,近红外发光,高分子
Abstract:
以1倍的三氯化铒(ErCl3)与2倍的8-羟基喹啉(Q)和1倍的5-(2-甲基丙烯酰乙氧基甲氧基)-8-羟基喹啉(HEMA-CH2-Q)反应合成了一种8-羟基喹啉铒络合物单体(ErQ2(HEMA-CH2-Q)),然后与N-乙烯基咔唑(NVK)通过自由基共聚合成了一种新型的高分子铒络合物(PCzErQ3).用元素分析、核磁共振谱(1H-NMR)、红外光谱(FTIR)、凝胶渗透色谱(GPC)、差示扫描量热法(DSC)、热重分析(TGA)、紫外-可见(UV-Vis)吸收光谱、光致发光(PL)光谱和荧光寿命等方法对其进行结构表征和性能测试.该高分子铒络合物能溶于一般的有机溶剂,具有较好的热稳定性.光致发光光谱表明,通过激发配位基团(8-羟基喹啉)和光捕获基团(咔唑),该高分子铒络合物能发射铒离子的特征近红外光,在光通信和生物医学等领域具有广阔的应用前景.
| [1] | 2 Thompson J,Blyth R I R,Gigli G,Cingolani R.Adv Funct Mater,2004,14:979~984
|
| [2] | 3 Uh H,Petoud S.CR Chim,2010;13(6-7):668~680
|
| [3] | 5 Katkova M A,Kurskii Y A,Fukin G K,Averyushkin A S,Artamonov A N,Vitukhnovsky A G,Bochkarev M N.Inorg Chim Acta,2005,358(13):3625~3632
|
| [4] | 8 Van Deun R,Fias P,Nockemann P,Schepers A,Parac-Vogt T N,Van Hecke K,Van Meervelt L,Binnemans K.Inorg Chem,2004,43(26):8461~8469
|
| [5] | 9 Sun L N,Zhang Y,Yu J B,Yu S Y,Dang S,Peng C Y,Zhang H J.Microporous Mesoporous Mater,2008,115:535~540
|
| [6] | 10 Sun L N,Zhang H J,Yu J B,Yu S Y,Peng C Y,Dang S,Guo X M,Feng J.Langmuir,2008,24:5500~5507
|
| [7] | 13 Suzuki H.J Photochem Photobio A:Chem,2004,166(1-3):155~161
|
| [8] | 15 Luo J X,Yang C L,Zheng J,Ma J Y,Liang L Y,Lu M G.Eur Polym J,2011,47:385~393
|
| [9] | 16 Wainwright M,Griffiths J,Guthrie J T,Gates A P,Murry D E.J Appl Polym Sci,1992,44:1179~1186
|
| [10] | 1 Sun L N, Zhang H J,Fu L S,Liu F Y,Meng Q G,Peng C Y,Yu J B.Adv Funct Mater,2005,15(6):1041~1048
|
| [11] | 4 Artizzu F,Marchio L,Mercuri M L,Pilia L,Serpe A,Quochi F,Orru R,Cordella F,Saba M,Mura A,Bongiovanni G,Deplano P.Adv Funct Mater,2007,17:2365~2376
|
| [12] | 6 Artizzu F,Deplano P,Marchio L,Mercuri M L,Pilia L,Serpe A,Quochi F,Orru R,Cordella F,Meinardi F,Tubino R,Mura A,Bongiovanni G.Inorg Chem,2005,44(4):840~842
|
| [13] | 7 Comby S,Imbert D,Vandevyver C,B黱zli J C G.Chem Eur J,2007,13(3):936~944
|
| [14] | 11 Sun L N,Dang S,Yu J B,Feng J,Shi L Y,Zhang H J.J Phys Chem B,2010,114:16393~16397
|
| [15] | 12 Suzuki H,Hattori Y,Iizuka T,Yuzawa K,Matsumoto N.Thin Solids Films,2003,438-439:288~293
|
| [16] | 14 Mei Q B,Du N Y,Lu M G.Eur Polym J,2007,43:2380~2386
|
| [17] | 17 Hebbink G A,Reinhoudt D N,van Veggel F C J M.Eur J Org Chem,2001,21:4101~4106
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
