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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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苯基聚倍半硅氧烷改性大豆油基聚氨酯的合成及其性能研究
DOI: 10.11777/j.issn1000-3304.2015.14256, PP. 290-297
Keywords: 苯基聚倍半硅氧烷,环氧大豆油,PEG-600,植物油聚氨酯,复合材料
Abstract:
以环氧大豆油为起始原料经开环反应合成出大豆油多元醇,并与聚乙二醇(PEG-600)互混作为多元醇原料制备出植物油基聚氨酯.在预聚体合成过程中,加入不同含量的七苯基三环庚硅氧烷三硅醇,通过醇羟基与异氰酸酯基的反应,将聚倍半硅氧烷(POSS)引入到植物油聚氨酯基体中,制备出聚氨酯(PU/POSS)纳米复合材料,并探讨纳米粒子—聚倍半硅氧烷对聚氨酯材料热稳定性,表面疏水性及力学性能的影响.热重分析(TGA)结果表明,在O2条件下,复合材料的初始降解温度Td5和最终稳定温度Tf都会提高,特别是当POSS含量达到9.27wt%后,聚氨酯在450~500℃之间较强的失重现象消失;DSC结果表明玻璃化温度Tg随粒子含量的增加呈现先增大后减小的趋势;静态接触角测试结果表明随POSS含量的增加,材料表面的疏水、疏油性随之增大.拉伸测试结果表明POSS的引入能在一定程度上提高材料的拉伸强度.
| [1] | 1 Voronkov M, Lavrent'yev V.Inorganic Ring Systems.Verlag Berlin Heidelberg:Springer,1982,199~236
|
| [2] | 2 Kuo S W,Chang F C.Prog Polym Sci,2011,36(12):1649~1696
|
| [3] | 7 Cai H,Xu K,Liu X,Fu Z,Chen M.Dalton Trans,2012,41(23):6919~6921
|
| [4] | 8 Xu H,Yang B,Wang J,Guang S,Li C.J Polym Sci,Part A:Polym Chem,2007,45(22):5308~5317
|
| [5] | 9 Gnanasekaran D,Walter P A,Reddy B.Polym Eng Sci,2013,53(8):1637~1644
|
| [6] | 10 Wu K,Kandola B K,Kandare E,Hu Y.Polym Compos,2011,32(3):378~389
|
| [7] | 11 Lichtenhan J D,Gilman J W.US patent,C08L,6 362279.2002-03-26
|
| [8] | 12 Bourbigot S,Turf T,Bellayer S,Duquesne S.Polym Degrad Stab,2009,94(8):1230~1237
|
| [9] | 13 Musto P,Abbate M,Pannico M,Scarinzi G,Ragosta G.Polymer,2012,53(22):5016~5036
|
| [10] | 14 Leu C M,Chang Y T,Wei K H.Chem Mater,2003,15(19):3721~3727
|
| [11] | 15 Wahab M A,Mya K Y,He C.J Polym Sci,Part A:Polym Chem,2008,46(17):5887~5896
|
| [12] | 17 Wang J,Ye Z,Joly H.Macromolecules,2007,40(17):6150~6163
|
| [13] | 18 Lee K M,Knight P T,Chung T,Mather P T.Macromolecules,2008,41(13):4730~4738
|
| [14] | 19 Frank K L,Exley S E,Thornell T L,Morgan S E,Wiggins J S.Polymer,2012,53(21):4643~465
|
| [15] | 20 Tan B H,Hussain H,Leong Y W,Lin T T,Tjiu W W,He C.Polym Chem,2013,4(4):1250~1259
|
| [16] | 21 Wang Z B,Leng S W,Wang Z G,Li G Y,Yu H.Macromolecules,2011,44(3):566~571
|
| [17] | 22 Huang J,Xiao Y,Mya K Y,Liu X,He C,Dai J,Siow Y P.J Mater Chem,2004,14(19):2858~2863
|
| [18] | 23 Markovic E,Clarke S,Matisons J,Simon G P.Macromolecules,2008,41(5):1685~1692
|
| [19] | 29 Fina A,Tabuani D,Frache A,Camino G.Polymer,2005,46(19):7855~7866
|
| [20] | 30 Baldi F,Bignotti F,Fina A,Tabuani D,Riccò T,J Appl Polym Sci,2007,105(2):935~943
|
| [21] | 31 Goseki R,Hirai T,Ishida Y,Kakimoto M-a,Hayakawa T.Polym J,2012,44(6):658~664
|
| [22] | 32 Ni C H,Ni G F,Zhang L P,Mi J Q,Yao B L,Zhu C P.J Colloid Interface Sci,2011,362:94~99
|
| [23] | 33 Ni Y,Zheng S.Macromolecules,2007,40(19):7009~7018
|
| [24] | 34 Baldi F,Bignotti F,Ricco L,Monticelli O,Riccò T.J Appl Polym Sci,2006,100(4):3409~3414
|
| [25] | 35 Ding Y,Chen G,Song J,Gou Y,Shi J,Jin R,Li Q.J Appl Polym Sci,2012,126:194~204
|
| [26] | 36 Madbouly S A,Otaigbe J U,Nanda A K,Wicks D A.Macromolecules,2007,40(14):4982~4991
|
| [27] | 37 Wei K,Wang L,Zheng S X.Polym Chem,2013,4(5):1491~1501
|
| [28] | 38 Raftopoulos K N,Janowski B,Apekis L,Pissis P,Pielichowski K,Polymer,2013,54(11):2745~2754
|
| [29] | 39 Che Y W,K E T,Mater Lett,2004,58:3716~3719
|
| [30] | 40 Wright M E,Petteys B J,Guenthner A J,Fallis S,Yandek G R,Tomczak S J,Minton T K,Brunsvold A.Macromolecules,2006,39(14):4710~4718
|
| [31] | 41 Kuo S W,Chang F C.Prog Polym Sci,2011,36(12):1649~1696
|
| [32] | 42 Lee Y J,Kuo S W,Huang W J,Lee H Y,Chang F C.J Polym Sci,Part B:Polym Phys,2004,42(6):1127~1136
|
| [33] | 43 Khoon P A,Choy S L,Sit F C.J Appl Polym Sci,2013,131(6):39967~29974
|
| [34] | 44 Puthanparambil D,Kimball C,Hsu S L.Chinese J Polym Sci,2009,27(4):447~454
|
| [35] | 45 Yu Xuehai(余学海),Chen Qingmin(陈庆民),Gen Kuisi(耿奎士),Yan Jinqiang(严锦强),Wang Yuanshen(王源身).Acta Polymerica Sinica(高分子学报),1989,(1):98~102
|
| [36] | 46 Tan Peiwen(谭培文),Xie Hongquan(谢洪泉).Acta Polymerica Sinica(高分子学报),1988,(3):196~201
|
| [37] | 47 Petrovic Z S.Polym Rev,2008,48(1):109~155
|
| [38] | 48 Guo A,Cho Y,Petrovi c ＇ Z S.J Polym Sci,Part A:Polym Chem,2000,38(21):3900~3910
|
| [39] | 49 Koh K,Sugiyama S,Mofinaga T,Ohno K,Tsujii Y,Fukuda T,Yamahiro M,Iijima T,Oikawa,H,Watanabe K,Miyashita T.Macromolecules,2005,38:1264~1270
|
| [40] | 50 Oaten M,Choudhury N R.Macromolecules,2004,38(15):6392~6401
|
| [41] | 51 Neumann D,Fisher M,Tran L,Matisons J G.J Am Chem Soc,2002,124(47):13998~13999
|
| [42] | 52 Lu Y S,Xia Y,Larock R C S.Prog Org Coat,2011,71(4):336~342
|
| [43] | 53 Wang Wenping(王文平),Ding Weilang(丁伟良),Lv Xiaoyong(吕晓勇),Yu Jian(俞建),Jiang Hang(江航).Polymer Material Science & Engineering(高分子材料科学与工程),2013,29(1):40~43
|
| [44] | 54 Chen Xiaojin(陈小金),Chen Xianhong(陈宪宏).Journal of Materials Science and Engineering(材料科学与工程学报),2005,23(6):929~932
|
| [45] | 55 Lu Chengyuyu(卢成渝),Tian Chunrong(田春蓉),Wang Jianhua(王建华).Material Review(材料导报),2010,24(10):111~114
|
| [46] | 56 Huitron-Rattinger E,Ishida K,Romo-Uribe A,Mather P T.Polymer,2013,54:3350~3362
|
| [47] | 24 Cardoen G,Coughlin E B,Macromolecules,2004,37:5123~5126
|
| [48] | 25 Kotal A,Si S,Paira T K,Mandal T K,J Polym Sci,Part A:Polym Chem,2008,46(3):1111-1123
|
| [49] | 26 Wang Z,Leng S,Wang Z,Li G,Yu H.Macromolecules,2011,44(3):566~574
|
| [50] | 27 Mather P T,Jeon H G,Romo-Uribe A,Haddad T S,Lichtenhan J D,Macromolecules,1999,32(4):1194~1203
|
| [51] | 28 Waddon A J,Zheng L,Farris R J,Coughlin E B.Nano Lett,2002,2(10):1149~1155
|
| [52] | 3 Tamaki R,Tanaka Y,Asuncion M Z,Choi J,Laine R M.J Am Chem Soc,2001,123(49):12416~12417
|
| [53] | 4 Ak M,Gacal B,Kiskan B,Yagci Y ,Toppare L.Polymer,2008,49(9):2202~2210
|
| [54] | 5 Neumann D,Fisher M,Tran L,Matisons J G.J Am Chem Soc,2002,124(47):13998~13999
|
| [55] | 6 Laine R M,Roll M F.Macromolecules,2011,44(5):1073~1109
|
| [56] | 16 Ye Y S,Yen Y C,Chen W Y,Cheng C C,Chang F C.J Polym Sci,Part A:Polym Chem,2008,46(18):6296~6304
|
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