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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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基于ATRP接枝改性木质素的研究进展
DOI: 10.11777/j.issn1000-3304.2015.15172, PP. 1363-1376
Keywords: 木质素,接枝共聚,改性,原子转移自由基聚合(ATRP)
Abstract:
木质素是仅次于纤维素的第二大可再生生物质资源,也是一种环境友好的有机高分子材料.原子转移自由基聚合(atomtransferradicalpolymerization,ATRP)是近年来迅速发展并有着重要应用价值的一种"活性"/可控自由基聚合技术.本文结合本课题组目前的研究工作和近几年的相关报道,简述了ATRP在木质素接枝共聚方面的最新研究进展.综述了采用ATRP对木质素接枝共聚改性的方法,并采用该方法在木质素表面接枝不同功能性单体,赋予木质素表面温敏性、离子响应性、气体开关和基因传递等多种特殊性能的研究概况.最后介绍了AGETATRP(activatorsgeneratedbyelectrontransferATRP)在木质素接枝共聚反应中的应用.
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