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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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聚(环三磷腈-co-4,4'-(9-芴)二苯酚)微球的制备及其稳定液体弹珠的性能研究
DOI: 10.11777/j.issn1000-3304.2015.15096, PP. 1421-1426
Keywords: 聚磷腈微球,交联,稳定剂,液体弹珠,气-液界面
Abstract:
以六氯环三磷腈和4,4'-(9-芴)二苯酚为共聚单体,三乙胺为缚酸剂,乙腈为溶剂,通过一步沉淀聚合制备了疏水性的交联聚(环三磷腈-co-4,4'-(9-芴)二苯酚)(PZHF)微球,通过傅立叶变换红外光谱仪(FTIR)、X射线光电子能谱仪(XPS)和扫描电子显微镜(SEM)对微球的化学结构和形貌进行了表征;进一步以该微球为稳定剂,通过包覆水滴成功制备了液体弹珠,研究了液体弹珠的静态稳定性以及共聚物微球在液体弹珠表面的分布情况,并考察了液体弹珠的气体透过性.结果表明,PZHF微球具有高度交联的有机-无机杂化结构,平均粒径为1.3μm,且微球表面较为粗糙,具有疏水性;用其包覆水滴可得到稳定的液体弹珠,微球在气-液界面上的排列较为疏松,使液体弹珠具有独特的气体透过性,外界气体可通过液体弹珠表面进入内部水相而不破坏弹珠自身的结构.
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