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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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无皂乳液聚合制备含铕荧光共聚物乳液的研究及其表征
DOI: 10.3724/SP.J.1105.2012.11401, PP. 923-928
Keywords: 稀土,荧光,无皂乳液聚合,荧光共聚物
Abstract:
以丙烯酸(AA)为第一配体、邻菲罗啉(Phen)为第二配体、Eu3+为中心离子,合成了一种可聚合的稀土铕配合物.以配合物单体、甲基丙烯酸甲酯、丙烯酰胺和对苯乙烯磺酸钠为共聚单体,通过无皂乳液聚合的方法,制备了含铕荧光共聚物乳液.采用红外光谱对共聚物的结构进行了表征,并探讨了配合物单体含量对共聚物乳液性能的影响.透射电子显微镜(TEM)和激光光散射粒度仪(PCS)测试结果表明,共聚物乳液形成了相对均一的球状结构,但随着配合物单体含量增加,共聚物微球粒径逐渐增大、分散性变差.采用荧光分光光度计测试了共聚物乳液的荧光性能,在594和619nm处出现Eu3+的特征发射光谱,且荧光强度随着配合物单体含量增加而增强.
| [1] | 3 Petoud S,Muller G,Moore E G,Xu J,Sokolnicki J,Riehl J P,Le U N,Cohen S M,Raymond K N.J Am Chem Soc,2006,129:77~83
|
| [2] | 4 Mei Qunbo(梅群波),Ni Xianhua(倪现花),Zhang Qianfeng(张千峰),Tong Bihai(童碧海).Acta Polymerica Sinica(高分子学报),2009,(5):478~482
|
| [3] | 6 Male N A H,Salata O V,Christou V.Synth Met,2002,126:7~10
|
| [4] | 8 Tan S T,Feng X M,Zhao B,Zou Y P,Huang X W.Mater Lett,2008,62:2419~2421
|
| [5] | 9 Yan B,Wang Q M.J Photochem Photobiol A,2008,197:213~219
|
| [6] | 18 Xu L,Ma Y F,Tang K Z,Tang Y,Liu W S,Tan M Y.J Fluoresc,2008,18:685~693
|
| [7] | 19 Wang Lianhui(汪联辉),Yang Mujie(杨慕杰).Acta Polymerica Sinica(高分子学报),2000,(1):19~26
|
| [8] | 20 Pan Y F,Zheng A N,Hu F Z,Xiao H N.J Appl Polym Sci,2006,100:1506~1510
|
| [9] | 21 Yan H G,Wang H H,He P,Shi J X,Gong M L.Inorg Chem Commun,2011,14:1065~1068
|
| [10] | 22 Hasegawa Y,Yamamuro M,Wada Y,Kanehisa N,Kai Y,Yanagida S.J Phys Chem A,2003,107:1697~1702
|
| [11] | 1 Petoud S, Cohen S M,Bünzli J C G,Raymond K N.J Am Chem Soc,2003,125:13324~13325
|
| [12] | 2 Zhao Y L,Zhao F Y,Li Q,Gao D Q.J Rare Earths,2006,24:18~22
|
| [13] | 5 Tang Jieyuan(唐洁渊),Zhang Wengong(章文贡).Acta Polymerica Sinica(高分子学报),2002,(4):479~486
|
| [14] | 7 Cheng B M,Deng Z B,Liang C J,Zhang Y Y,Hao J G,Xu D H,Xiao J,Wang R F.J Rare Earths,2006,24:529~532
|
| [15] | 10 Garcia I T S,Ribeiro P V,Corrêa D S,da Cunha I M N,Carreêo N L V,Moreira E C,Rodembusch F S.Appl Surf Sci,2011,258:1437~1442
|
| [16] | 11 Wang Y J,Jiang H L.Mater Lett,2007,61:2779~2782
|
| [17] | 12 Allard E,Larpent C.J Polym Sci Part A:Polym Chem,2008,46:6206~6213
|
| [18] | 13 Wang B D,Yang Z Y,Zhang D W,Wang Y.Spectrochim Acta Part A,2006,63:213~219
|
| [19] | 14 Jiang Y N,Li H,Meng X S,Zhao D F,Wang Y Y,Liu Q,Zheng J,Zhang J H,Lin Q,Yang B.J Rare Earths,2008,26:932~934
|
| [20] | 15 Wang Dongmei(王冬梅),Lin Quan(林权),Xie Zhenguo(谢振国),Chu Zhenxing(储振兴),Zhang Junhu(张俊虎),Yang Bai(杨柏).Acta Polymerica Sinica(高分子学报),2004,(3):313~316
|
| [21] | 16 O'Riordan A,O'Connor E,Moynihan S,Llinares X,van Deun R,Fias P,Nockemann P,Binnemans K,Redmond G.Thin Solid Films,2005,491:264~269
|
| [22] | 17 O'Riordan A,O'Conno E,Moynihan S,Nockemann P,Fias P,van Deun R,Cupertino D,Mackie P,Redmond G.Thin Solid Films,2006,497:299~303
|
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