|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
聚合物熔体界面分子链扩散的流变学研究
DOI: 10.3724/SP.J.1105.2013.12261, PP. 361-366
Keywords: 界面扩散,流变学响应,频率依赖行为,聚合物熔体
Abstract:
以2种完全相容的多分散的聚合物树脂为研究对象,利用动态流变学手段实现了界面分子链扩散过程的实时检测.研究结果发现,完全相容的聚合物树脂之间的扩散动力学参数α具有相对分子质量差异的依赖性,两者之间相对分子质量差异越大,α值越大.通过流变学参数还可获得另一扩散动力学参数—特征时间tc,从而得以计算出组分之间扩散系数,研究结果表明所获得的扩散系数具有频率依赖性.
| [1] | 1 de Gennes P G. J Chem Phys,1971,55:572~579
|
| [2] | 2 Agrawal G,Wool R P,Dozier W D,Felcher G P,Zhou J,Pispas S,Mays J W,Russell T P.J Polym Sci Pol Phys,1996,34:2919~2940
|
| [3] | 4 Geoghegan M,Jones R,van der Grinten M,Clough A.Polymer,1999,40:2323~2329
|
| [4] | 5 Green P F,Doyle B L.Macromolecules,1987,20:2471~2474
|
| [5] | 6 Kanetakis J,Fytas G.Macromolecules,1989,22:3452~3458
|
| [6] | 7 Lamnawar K,Baudouin A.Eur Polym J,2010,46:1604 ~1622
|
| [7] | 11 Horiuchi S,Hanada T,Yase K,Ougizawa T.Macromolecules,1999,32:1312~1314
|
| [8] | 12 Juliac E,Arman J,Harran D.Eur Polym J,2002,38:2161~2169
|
| [9] | 13 Summerfield G C,Ullman R.Macromolecules,1987,20:401~404.
|
| [10] | 15 Cao Q,Song Y H,Tan Y Q,Zheng Q T.Polymer,2009,50:6350~6356
|
| [11] | 16 Wu Y,Yu W.J Colloid Interf Sci,2006,298:889~898
|
| [12] | 17 Yu W,Zhou Z X.Polymer,2012,53:881~890
|
| [13] | 18 Lim Y T,Park O O.Rheol Acta,2001,40:220~229
|
| [14] | 19 Kuleznev V N,Kandyrin L B.Vysokomol Soedin,2000,42:711~719
|
| [15] | 22 Yang L,Suo T C,Niu Y H,Wang Z G.Polymer,2010,51:5276~5281
|
| [16] | 23 Li Wenlin(李文林),Niu Yanhua(牛艳华),Wang Zhigang(王志刚),Zhang Jun(张军).Acta Polymerica Sinica(高分子学报),2012,(9):1007~1014
|
| [17] | 24 Qiu H,Bousmina M.J Rheol,1999,43:551~568
|
| [18] | 25 Bousmina M,Qiu H,Grmela M.Macromolecules,1998,31:8273~8280
|
| [19] | 26 Wang S F,von Meerwall E D,Wang S Q.Macromolecules,2004,37:1641~1651
|
| [20] | 3 Composto R J,Kramer E J,White D M.Nature,1987,328:234~236
|
| [21] | 8 Pierce F,Perahia D.Macromolecules,2009,42:7969~7973
|
| [22] | 9 Welp K A,Wool R P,Satija S K,Pispas S.Macromolecules,1998,31:4915~4925
|
| [23] | 10 Doi M,Graessley W W,Helfand E,Pearson D S.Macromolecules,1987,20:1900~1906
|
| [24] | 14 Song Y H,Yamamoto H,Nemoto N.Macromolecules,2004,37:6219~6226
|
| [25] | 20 Shen Lie(沈烈),Meng Qingrong(孟庆荣),Peng Mao(彭懋),Fang Zhengping(方征平).Acta Polymerica Sinica(高分子学报),2012,(8):794~800
|
| [26] | 21 Niu Y H,Wang Z G.Macromolecules,2006,39:4175~4183
|
| [27] | 27 Qiu H,Bousmina M.Macromolecules,2000,33:6588~6594
|
| [28] | 28 Thompson R L,McDonald M,Lenthall J T.Macromolecules,2005,38:4339~4344
|
| [29] | 29 Kramer E J,Green P F,Palmstrom C J.Polymer,1984,25:473~480
|
| [30] | 30 Jordan E A,Ball R C,Donald A M.Macromolecules,1988,21:235~239
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
