|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
硅烷功能化石墨烯/硅树脂纳米复合材料的制备与表征
DOI: 10.3724/SP.J.1105.2013.12204, PP. 327-334
Keywords: 功能化石墨烯,硅树脂,复合材料,拉伸强度,热稳定性
Abstract:
先用乙烯基三甲氧基硅烷(A-171)和二甲肼改性并还原氧化石墨烯(GO),制备A-171功能化的石墨烯(FG).研究结果表明A-171与GO上的羟基发生了反应,以共价键连接到了石墨烯的表面;FG能在四氢呋喃中均匀分散并且剥离成厚度约为0.9nm的单一片层,其干燥后表面呈褶皱状.然后将FG与双组分硅树脂用溶液共混法制备了FG/硅树脂纳米复合材料.运用X射线衍射、扫描电子显微镜、动态热机械分析、拉伸试验等手段分析了复合材料的形态与性能,结果表明,与未处理过的石墨烯相比,FG在复合材料中有更好的分散和更强的界面作用.含0.5wt%FG的复合材料的拉伸强度较硅树脂提高了87.7%,玻璃化温度提高了23.9℃,失重5%时的温度也提高了20.1℃.
| [1] | 1 Ramanathan T, Stankovich S,Dikin D A,Liu H,Shen H,Nguyen S T,Brinson L C.J Polym Sci B Polym Phys,2007,45(15):2097~2112
|
| [2] | 2 Li Y,Kuan C,Chen C,Kuan H,Yip M,Chiu S,Chiang C.Mater Chem Phys,2012,134(2-3):677~685
|
| [3] | 3 Eda G,Chhowalla M.Nano Lett,2009,9(2):814~818
|
| [4] | 5 Kalaitzidou K,Fukushima H,Drzal L.Compos Sci Technol,2007,67(10):2045~2051
|
| [5] | 6 Cao Y,Feng J,Wu P.Carbon,2010,48(5):1683~1685
|
| [6] | 7 Liang J,Huang Y,Zhang L,Wang Y,Ma Y,Guo T,Chen Y.Adv Funct Mater,2009,19(14):2297~2302
|
| [7] | 8 Zhao X,Zhang Q,Chen D.Macromolecules,2010,43(5):2357~2363
|
| [8] | 12 Verdejo R,Barroso-Bujans F,Rodriguez-Perez M A,de Saja J A,Lopez-Manchado M A.J Mater Chem,2008,18(19):2221~2226
|
| [9] | 13 Yang H,Li F,Shan C,Han D,Zhang Q,Niu L,Ivaska A.J Mater Chem,2009,19(26):4632~4638
|
| [10] | 15 Pham V H,Cuong T V,Hur S H,Oh E,Kim E J,Shin E W,Chung J S.J Mater Chem,2011,21(10):3371~3377
|
| [11] | 17 Ma Wenshi(马文石),Zhou Junwen(周俊文).Chem J Chin Univ(高等学校化学学报),2010,31(10):1982~1986
|
| [12] | 18 Liu J,Jeong H,Liu J,Lee K,Park J,Ahn Y H,Lee S.Carbon,2010,48(8):2282~2289
|
| [13] | 19 Ma Wenshi(马文石),Zhou Junwen(周俊文),Lin Xiaodan(林晓丹).Acta Chim Sinica(化学学报),2011,69(12):1463~1468
|
| [14] | 20 Zarrin H,Higginst D,Jun Y,Chen Z,Fowler M.J Phys Chem C,2011,115(42):20774~20781
|
| [15] | 21 Hou S,Su S,Kasner M L,Shah P,Patel K,Madarang C J.Chem Phys Lett,2010,501(1-3):68~74
|
| [16] | 23 Zhu Y,Stoller M D,Cai W,Velamakanni A,Piner R D,Chen D,Ruoff R S.ACS Nano,2010,4(2):1227~1233
|
| [17] | 24 Stankovich S,Dikin D A,Dommett G H B,Kohlhaas K M,Zimney E J,Stach E A,Piner R D,Nguyen S T,Ruoff R S.Nature,2006,442:282~286
|
| [18] | 25 Wang Z,Tang X,Yu Z,Guo P,Song H,Du X.Chinese J Polym Sci,2011,29(3):368~376
|
| [19] | 26 Cai D,Song M.J Mater Chem,2010,20(37):7906~7915
|
| [20] | 4 Ma H,Zhang H,Hu Q,Li W,Jiang Z,Yu Z,Dasari A.ACS Appl Mater Interfaces 2012,4(4):1948~1953
|
| [21] | 9 Bao C,Guo Y,Song L,Kan Y,Qian X,Hu Y.J Mater Chem,2011,21(35):13290~13298
|
| [22] | 10 Wang X,Xing W,Zhang P,Song L,Yang H,Hu Y.Compos Sci Technol,2012,72(6):737~743
|
| [23] | 11 Wang X,Dou W.Thermochim Acta,2012,529:25~28
|
| [24] | 14 Hummers W S,Offeman R E.J Am Chem Soc,1958,80(6):1339~1339
|
| [25] | 16 Li D,Muller M B,Gilje S,Kaner R B,Wallace G G.Nature Nanotechnol,2008,3:101~105
|
| [26] | 22 Vast L,Mekhalif Z,Fonseca A,Nagy J B,Delhalle J.Compos Sci Technol,2007,67(5):880~889
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
