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OALib Journal期刊
ISSN: 2333-9721
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无皂种子乳液聚合制备含稀土磁性荧光微球及其表征
DOI: 10.3724/SP.J.1105.2013.13095, PP. 1453-1458
Keywords: 稀土配合物,无皂种子乳液聚合,磁性荧光微球
Abstract:
以FeCl3？6H2O和FeCl2？4H2O为原料,通过化学共沉淀方法制备Fe3O4磁性纳米粒子,用油酸和十一烯酸钠对纳米粒子进行双重改性,得到固含量为4%的稳定水基磁流体.在该磁流体存在下,以苯乙烯和甲基丙烯酸缩水甘油酯为单体进行无皂乳液聚合,制备出磁性种子微球;在种子磁性微球存在下,以对苯乙烯磺酸钠,稀土配合物等为功能单体,通过无皂种子乳液聚合法制备磁性荧光微球,该微球表现出优异的磁学性能以及荧光性能.用傅立叶红外光谱仪、透射电子显微镜、X射线衍射仪、振动样品磁强计、荧光分光光度计对磁性荧光微球结构形貌以及磁性荧光性能表征.测试结果表明,所制备的种子微球以及磁性荧光微球呈良好的单分散性,Z均粒径分别为147nm和228nm,热重分析表明磁性荧光微球中Fe3O4的含量为4.7%,与之对应的饱和磁化强度为0.396emu/g,在595nm和619nm处观测到Eu3+的特征发射光谱.
| [1] | 7 Guo Feige(郭飞鸽),Zhang Qiuyu(张秋禹),Luo Shaobing(罗绍兵),Zhang Hepeng(张和鹏).Acta Polymerica Sinica(高分子学报),2008,(11):1082~1088
|
| [2] | 8 Zhou Chunhua(周春华),Liu Wei(刘威),Zhang Shuxiang(张书香),Li Hui(李辉),Chu Guohong(褚国红).Acta Polymerica Sinica(高分子学报),2005,(4):606~610
|
| [3] | 9 Vollath D.Adv Mater,2010,22:4410~4415
|
| [4] | 10 Allendorf M D,Bauer C A,Bhakta R K,Houk R J T.Chem Soc Rev,2009,38:1330~1352
|
| [5] | 11 Wang Z X,Wu L M,Chen M,Zhou S X.J Am Chem Soc,2009,131:11276~11277
|
| [6] | 12 Hu D,Chen M,Gao Y,Li F Y,Wu L M.J Mater Chem,2011,21:11276~11282
|
| [7] | 13 Zhou Yingjie(周英杰),Zhu Haie(朱海娥),Zhang Jun(张俊),Yi Changfeng(易昌凤),Xu Zushun(徐祖顺).Acta Polymerica Sinica(高分子学报),2012,(9):923~928
|
| [8] | 14 Wang Y,Ji L,Zhang B B,Yin P H,Qiu Y Y,Song D Q,Zhou J Y,Li Q.Nanotechnology,2013,24:175101~17509
|
| [9] | 15 Cai Lifeng(蔡力锋),Wen Yuqian(温裕乾),Lin Zhiyong(林志勇),Qian Hao(钱浩),Deng Xiongwei(邓雄威).Acta Polymerica Sinica(高分子学报),2012,(8):846~851
|
| [10] | 16 Rong Jianhua(荣建华),Duan Taiwei(段泰炜),Wen Hongge(温鸿戈),Qu Xiaozhong(屈小中).Acta Polymerica Sinica(高分子学报),2010,(4):484~48917 Hang Mengqiong(黄孟琼),Wang Xiuling(王秀玲),Liu Yongjian(刘勇健).Acta Chimica Sinica(化学学报),2010,16:1623~1628
|
| [11] | 18 Liu Xin(刘欣),Zheng Chengzhi(郑成志),Yang Yixian(杨逸仙),Liang Jiangong(梁建功),Han Heyou(韩鹤友).Acta Chimica Sinica(化学学报),2010,(8):793~797
|
| [12] | 19 Zhu H E,Tao J,Wang W,Zhou Y J,Li P H,Li Z,Yan K,Wu S L,Yeung K W K,Xu Z S,Xu H B,Chu P K.Biomaterials,2013,34:2296~2306
|
| [13] | 20 Hu X X,Li P H,Yeung K W K,Chu P K,Wu S L,Xu Z S.J Polym Sci Part A Polym Chem,2010,48:5961~5967
|
| [14] | 21 Schladt T D,Schneider K,Schild H,Tremel W.Dalton Trans,2011,40:6315~6343
|
| [15] | 1 Gu H W, Xu K M,Xu C J,Xu B.Chem Commun,2006,941~949
|
| [16] | 2 Lee J E,Lee N,Kim H,Kim J,Choi S H,Kim J H,Kim T,Song I C,Park S P,Moon W K,Hyeon T.J Am Chem Soc,2009,132:552~557
|
| [17] | 3 Yang X Q,Chen Y H,Yuan R X,Chen G H,Blanco E,Gao J M,Shuai X T.Polymer,2008,49:3477~3485
|
| [18] | 4 Kievit F M,Zhang M.Acc Chem Res,2011,44:853~862
|
| [19] | 5 Laurent S,Forge D,Port M,Roch A,Robic C,Vander Elst L,Muller R N.Chem Rev,2009,110:2574~2574
|
| [20] | 6 Koole R,Mulder W J M,Schooneveld M M,Strijkers G J,Meijerink A,Nicolay K.Wiley Interdiscip Rev Nanomed Nanobiotechnol,2009,1:475~491
|
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