|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
一种硅烷偶联剂的合成及其在白炭黑/天然橡胶复合材料中的应用
DOI: 10.3724/SP.J.1105.2014.13189, PP. 202-209
Keywords: 防老化,硅烷偶联剂,白炭黑表面改性,白炭黑/NR复合材料
Abstract:
采用γ-缩水甘油醚氧丙基三甲氧基硅烷（A187）与对氨基二苯胺（PPDA）反应，制备得到一种具有防老化功能的硅烷偶联剂，并通过1H-NMR、IR和MS对其结构进行表征.之后，将不同用量的硅烷偶联剂用于原位改性白炭黑制备防老功能化白炭黑/天然橡胶（NR）复合材料，并与相应的炭黑/NR、未改性白炭黑/NR及双-（γ-三乙氧基硅基丙基）四硫化物（Si69）改性白炭黑/NR在加工性能、增强性能和防老化性能方面进行对比.硫化特性数据表明，防老偶联剂的添加使复合材料的黏度降低，最大转矩增加，正硫化时间缩短.动态黏弹性能显示，改性后白炭黑的分散性得到明显提高.复合材料的力学性能先随防老偶联剂用量的增加而提高，之后到达平台.当防老偶联剂的用量大于或等于白炭黑质量的10.8%时，复合材料的拉伸强度与炭黑/NR、Si69改性白炭黑/NR相当，远大于未改性白炭黑/NR的强度；而其撕裂强度都大于3种对比复合材料.经过100℃下不同天数的热氧老化后，添加防老偶联剂的复合材料表现出良好的性能保持率，优于添加防老剂4020的3种对比材料，表明防老偶联剂具有更好的防护效果.
| [1] | 8 Hair M L, Hertl W.J Phys Chem, 1970, 74(1):91~94
|
| [2] | 10 Wolff S.Rubber Chem Technol, 1996, 69:325~345
|
| [3] | 11 Reuvekamp L A E M, Brinke J W T, Swaaij P J V.Kautschuk Gummi Kunststoffe, 2002, 55(5):41~47
|
| [4] | 12 Luginsland H D, Hueth K.Kautschuk Gummi Kunststoffe, 2000, 53(1):10~23
|
| [5] | 13 Yan H X, Sun K, Zhang Y X.J Appl Polym Sci, 2004, 94(6):64~68
|
| [6] | 14 Wang Can(王灿), Wan Shaoyang(阮少阳), Yin Chao(尹超).China Rubber Science and Technology Market(橡胶科技市场), 2011, 10:8~12
|
| [7] | 15 Jia Hongbing(贾红兵), Jin Zhigang(金志刚), Ji Qingmin(吉庆敏), Wang Ying(王颖), Zhang Shiqi(张士齐).China Rubber Industry(橡胶工业), 1999, 46(19):590~593
|
| [8] | 24 Ansarifar A, Wang L, Ellis R J, Kirtley S P, Riyazeddin N.J Appl Polym Sci, 2007, 105(2):322~32
|
| [9] | 1 Idrus S S, Ismail H, Palaniandy S.Polym Test, 2011, 30(2):251~259
|
| [10] | 2 Ramorino G, Bignotti F, Pandini S, Riccò T.Compos Sci Technol, 2009, 69(7-8):1206~1211
|
| [11] | 3 Guo B C, Chen F, Lei Y D, Liu X L, Wan J J, Jia D M.Appl Sur Sci, 2009, 255:7329~7336
|
| [12] | 4 Wagner M P.Rubber Chem Technol, 1976, 49:703~704
|
| [13] | 5 Zhang M L, Ding L G, Jing X Y, Hou X Q.Chem Eng, 2003, 6:11~14
|
| [14] | 6 Schuring D J, Futamura S.Rubber Chem Techn, 1990, 63:315~367
|
| [15] | 7 Wolff S, Gǒrl U, Wang M J, Wolff W.Eur Rubber J, 1994, 176(1):16~19
|
| [16] | 9 Hockey J A, Pethica B A.Trans Faraday Soc, 1961, 57:2247~2262
|
| [17] | 16 Sulekha P B, Joseph R, Manjooran K B.J Appl Polym Sci, 2004, 93(1):437~443
|
| [18] | 17 Abd El-Aziz El-Wakil, Mirham A B.J Appl Polym Sci, 2011, 119(4):2461~2467
|
| [19] | 18 Sulekha P B, Joseph R, George K E.Polym Degrad Stabil, 1999, 63(2):225~230
|
| [20] | 19 Sulekha P B, Joseph R, Madhusoodanan K N, Thomas K T.Polym Degrad Stabil, 2002, 77(3):403~416
|
| [21] | 20 Sulekha P B, Joseph R, Prathapan S.J Appl Polym Sci, 2001, 81(9):2183~2189
|
| [22] | 21 Liauw C M, Allen N S, Edge M, Lucchese L.Polym Degrad Stabil, 2001, 74(1):159~166
|
| [23] | 22 Pan Q W, Wang B B, Chen Z H, Zhao J Q.Mater Design, 2013, 50:558~565
|
| [24] | 23 Pan Q W, Wang B B, Chen Z H.Acta Materiae Compositae Sinica, 2013, 30(5)
|
| [25] | 25 Ramier J., Gauthier C, Chazeau L, Stelandrel L, Guy L.J Polym Sci:Part B:Polym Phy, 2007, 45:286~298
|
| [26] | 26 Bertora A, Castellano M, Marsano E, Alessi M, Conzatti L, Stagnaro P, Colucci G, Priola A, Turturro A.Macromol Mater Eng, 2011, 296:455~464
|
| [27] | 27 Yang Qingzhi(杨清芝).Practical Rubber Technology(实用橡胶工艺学).1st ed(第一版).Beijing(北京):Chemical Industry Press(化学工业出版社), 2005.71~72
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
