OALib Journal期刊
ISSN: 2333-9721
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聚乙烯醇/明胶/纳米羟基磷灰石复合材料热塑加工性能研究
DOI: 10.11777/j.issn1000-3304.2014.13416, PP. 956-962
Keywords: 聚乙烯醇,纳米羟基磷灰石,明胶,热塑加工
Abstract:
结合固相剪切碾磨技术(S3M),以胶原纤维(Col)在熔融挤出过程中原位降解成明胶(Gel),通过Gel与聚乙烯醇(PVA)分子间形成氢键复合增塑PVA,改善聚乙烯醇/纳米羟基磷灰石(PVA/n-HA)复合材料的热塑加工性能.采用扫描电子显微镜(SEM)、傅里叶变换红外光谱仪(FTIR)、示差扫描量热仪(DSC)、热重分析仪(TGA)、X射线衍射仪(XRD)和高压毛细管流变仪等研究了复合材料的结构与热塑加工性能.结果表明,通过S3M技术实现了n-HA在PVA基体中的均匀分散;FTIR表明Gel与PVA间形成了氢键作用和部分接枝反应;Gel和PVA分子间的氢键作用使PVA/Gel/n-HA复合材料的初始分解温度提高到287.6℃,改善了PVA的热稳定性,PVA的结晶度由纯PVA的58.2%降低到复合材料中的24.5%,使其熔点降低至130.5℃,拓宽了PVA/n-HA复合材料的加工范围,获得超过140K的热塑加工窗口.Gel有效降低了PVA/n-HA复合材料表观黏度,改善了PVA/n-HA复合材料的热塑加工性能.
References
[1] | 1 Zheng Y D, Lv H X,Wang Y J,Lu H D,Liu Q,Xi T F.Biomed Mater,2009,4:1~7
|
[2] | 9 Wang Qi(王琪),Li Li(李莉),Chen Ning(陈宁),Liu Yuan(刘渊),Bai Shibing(白时兵).Acta Polymerica Sinica(高分子学报),2011,9(9):932~938
|
[3] | 10 Wang Qi(王琪),Li Li(李莉),Chen Ning(陈宁),Bai Shibing(白时兵).Polymer Materials Science & Engineering(高分子材料科学与工程),2014,30(2):192~197
|
[4] | 11 Wang Xi(王郗),Yang Yujun(杨玉军),Li Li(李莉).Acta Polymerica Sinica(高分子学报),2013,(10):1247~1252
|
[5] | 12 Chen Xiao(陈晓),Chen Ning(陈宁),Wang Qi(王琪).Polymer Bulletin(高分子通报),2013,(6):26~32
|
[6] | 13 Liu Y S,Wang Q,Li L.J Soc Leath Tech Ch,2012,96:106~113
|
[7] | 14 Wang Jianhua(王建华),Wei Yali(卫亚丽),Wen Zonghe(文宗河),He Jianchuan(何建川).Chemistry(化学通报),2004,(7):482~486
|
[8] | 15 Asran A S,Henning S,Michler G H.Polymer,2010,51:868~876
|
[9] | 16 Wang F,Guo E Y,Song E M,Zhao P,Liu J J.Adv Biosci Biotechnol,2010,1:185~189
|
[10] | 17 Assender H E,Windle A H.Polymer,1998,39:4295~4302
|
[11] | 18 Hong P D,Chen J H,Wu H L.J Appl Polym Sci,1998,69(12):2477~2486
|
[12] | 19 Wu G,Su B,Zhang W,Wang X.Mater Chem Phys,2008,107:364~369
|
[13] | 20 Holland B J,Hay J N.Polymer,2001,42:6775~6783
|
[14] | 2 Xu Fenglan(许凤兰),Li Yubao(李玉宝),Wang Xuejiang(王学江),Zuo Yi(左奕),Han Jing(韩劲).J Funct Mater(功能材料),2004,35(4):509~512
|
[15] | 3 Pan Y S,Xiong D S.J Mater Sci,2010,45:5495~5501
|
[16] | 4 Wang Yingjun(王迎军),Liu Qing(刘青),Zheng Yudong(郑裕东),Wu Gang(吴刚).Chinese Journal of Biomedical Engineering(中国生物医学工程学报),2005,24(2):150~153
|
[17] | 5 Xu Xi(徐僖),Wang Qi(王琪),Mechanochemical Reactor(力化学反应器):China,95111258.9[P].2001-04-19
|
[18] | 6 Xu X,Wang Q,Kong X A.Plast,Rubber Compos,1996,25(3):152~158
|
[19] | 7 Wang Qi(王琪),Lu Canhui(卢灿辉),Xia Hesheng(夏和生).Polymer Bulletin(高分子通报),2013,(9):35~49
|
[20] | 8 Bekturov E A,Bimedina L A.Adv Polym Sci,1981,41:99~147
|
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