|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
无模板法聚苯胺纳米管的制备及表征
DOI: 10.11777/j.issn1000-3304.2014.13417, PP. 938-942
Keywords: 聚苯胺,纳米管,无模板法,形貌
Abstract:
以过硫酸铵（APS）为氧化剂，在无模板，无掺杂酸条件下，利用超声辅助合成了聚苯胺纳米管.通过透射电子显微镜、傅里叶红外光谱、紫外-可见光谱、X-射线衍射对产物的形貌、结构和性能进行了表征.研究表明，形成的聚苯胺纳米管内径约为10nm，外径约为80nm，长度约为26μm，且管径均匀.苯胺单体浓度越高，聚合速率越快.但是，聚苯胺的形貌与苯胺单体的浓度无关，而与苯胺和过硫酸铵的摩尔比有关.超声在纳米管的形成中起主要作用，它阻止球状胶束无规则团聚，使得在较高的苯胺浓度下（0.2mol/L）也可形成纳米管.合成的聚苯胺电导率为5×10-3S·cm-1，结晶度不高.
| [1] | 22 Laslau C,Zujovic Z D,Travas-Sejdic J.Macromol Rapid Comm,2009,30:1663~1668
|
| [2] | 23 Huang Y F,Lin C W.Polymer,2009,50(3):775~782
|
| [3] | 24 Zhang L J,Long Y Z,Chen Z J,Wan M X.Adv Funct Mater,2004,14(7):693~698
|
| [4] | 25 Xiao H M,Zhang W D,Lv C,Fu S Y,Wan M X,Mai Y W.Macromol Chem Phys,2010,211(9):1109~1116
|
| [5] | 1 Wang H J, Ji L W,Li D F,Wang J Y.J Phys Chem B,2008,112(9):2671~2677
|
| [6] | 2 Shin Y J,Kameoka J J.Ind Eng Chem,2012,18(1):193~197
|
| [7] | 3 Du M,Yang T,Li X,Li X,Jiao K.Talanta,2012,88:439~444
|
| [8] | 4 Huan T N,Ganesh T,Han S H,Yoon M Y,Chung H.Biosens Bioelectron,2011,26(10):4227~4230
|
| [9] | 5 Sreedhar B,Radhika P,Neelima B.Polym Adv Technol,2009,20:950~958
|
| [10] | 6 Wei Yen(危岩),Li Baosong(李保松),Fu Changkui(付长奎),Qi Hongxu(齐宏旭).Acta Polymerica Sinica(高分子学报),2010,(12):1399~1405
|
| [11] | 7 Xia H B,Tao X T.J Mater Chem,2011,21(8):2463~2465
|
| [12] | 8 Fryczkowski R,Kowalczyk T.Synthetic Met,2009,159(21-22):2266~2268
|
| [13] | 9 Prabhakaran M P,Ghasemi-Mobarakeh L,Jin G R.J Biosci Bioeng,2011,112(5):501~507
|
| [14] | 10 Martin C R.Chem Mater,1996,8(8):1739~1746
|
| [15] | 11 Li X,Wan M X,Li X N,Zhao G L.Polymer,2009,50(19):4529~4534
|
| [16] | 12 Carswell A D W,O'Rear E A,Grady B P.J Am Chem Soc,2003,125(48):14793~14800
|
| [17] | 13 Wang X,Liu N,Yan X,Zhang W J,Wei Y.Chem Lett,2005,34(1):42~43
|
| [18] | 14 Bartlett P N,Birkin P R,Ghanem M A,Toh C S.J Mater Chem,2001,11:849~853
|
| [19] | 15 Zhang Z M,Wei Z X,Zhang L J,Wan M X.Acta Mater,2005,53(5):1373~1379
|
| [20] | 16 Ding Hangjun(丁杭军),Zhu Changjin(朱长进),Zhou Zhiming(周智明),Wan Meixiang(万梅香),Acta Polymerica Sinica(高分子学报),2007,(5):462~466
|
| [21] | 17 Lu Qi(路崎),Zhao Qiang(赵强),Zhang Hongming(张红明),Li Ji(李季),Wang Xianhong(王献红),Wang Fosong(王佛松),Acta Polymerica Sinica(高分子学报),2012,(8):1080~1084
|
| [22] | 18 Wan M X.Adv Mater,2008,20(15):2926~2932
|
| [23] | 19 Ding H J,Shen J Y,Wan M X,Chen Z J.Macromol Chem Phys,2008,209(8):864~871
|
| [24] | 20 Zhang Z M,Wei Z X,Wan M X.Macromolecules,2002,35(15):5937~5942
|
| [25] | 21 Zhang D H,Wang Y Y.Mater Sci Eng B,2006,134(1):9~19
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
