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含噻吩[2,3-b]并噻吩-吡咯[3,4-c]并吡咯二酮结构单元聚合物的合成及其在太阳能电池中的应用研究

DOI: 10.11777/j.issn1000-3304.2014.14110, PP. 1613-1621

Keywords: 交叉共轭聚合物,吡咯并吡咯,噻吩并噻吩,有机太阳能电池,聚合物半导体

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Abstract:

设计并合成了一种交叉共轭的(cross-conjugated)缺电子型聚合物单体——二溴代噻吩[2,3-b]并噻吩-吡咯[3,4-c]并吡咯(DPPTTZ)二酮,并将其分别与噻吩(T)、硒吩(Se)和N-甲基吡咯(Py)的双锡试剂进行共聚反应,获得了一类新的供体-受体(D-A)型共轭聚合物光电材料.这类材料分子的最高占有轨道(HOMO)能级较低,因此其光电器件具有较高的开路电压(Voc),稳定性好.此外,它们在紫外-可见光区有较宽的吸收,最大吸收位于波长620nm附近;能带隙(bandgap)小,分别为1.86eV(pDPPTTZ-T)、1.83eV(pDPPTTZ-Se)和1.85eV(pDPPTTZ-Py).器件初步测试结果表明,上述聚合物与PC71BM组成的本体异质结聚合物太阳能电池Voc在0.68~0.81V之间,能量转化效率(PCE)最高达3.05%(pDPPTTZ-T).

 References

[1]  1 Li G, Zhu R,Yang Y.Nat Photonics,2012,16:153~161
[2]  2 Zhang Tianhuia(张天慧),Piao Lingyu(朴玲钰),Zhao Suling(赵谡玲),Xu Zheng(徐征),Yang Lei(杨磊),Liu Xiangzhi(刘祥志),Ju Siting(鞠思婷).Chinese J Org Chem(有机化学),2011,31(2):260~272
[3]  3 Beaujuge P M,Fréchet J M.J Am Chem Soc,2011,133:20009~20029
[4]  4 Zhang Zhenghua(张正华),Li Linglan(李陵岚),Ye Chuping(叶楚平),Yang Pinghua(杨平华).Organic Solar Cell and Plastic Solar Cell(有机太阳电池与塑料太阳电池).Beijing(北京):Chemical Industry Press(化学工业出版社).2006.102~133
[5]  5 Li Zaifan(李在房),Peng Qiang(彭强),He Ping(和平),Wang Yanling(王艳玲),Hou Qiufei(侯秋飞),Li Benlin(李本林),Tian Wenjing(田文晶).Chinese J Org Chem(有机化学),2012,32:834~851
[6]  6 Fu Yu(付钰),Wang fang(王芳),Zhang Yan(张燕),Fang Xu(方旭),Lai Wanyong(赖文勇),Huang Wei(黄维).Acta Chim Sinica(化学学报),2014,72:158~170
[7]  7 Bundgaard E,Krebs F C.Solar Energy Materials & Solar Cells,2007,91:954~985
[8]  8 Zhang Qinghui(张庆辉),Yang Mujie(杨慕杰),Lu Shengli(路胜利).Polymer Materials Science And Engineering(高分子材料科学与工程),2005,21(1):11~14
[9]  9 Bérubé N,Gaudreau J,C？té M.Macromolecules,2013,46:6873~6880
[10]  17 Meager I,Ashraf R S,Rossbauer S,Bronstein H,Donaghey E J,Marshall J,Schroeder C B,Heeney M,Anthopoulos D T,McCulloch I.Macromolecules,2013,46:5961~5967
[11]  18 Letizia A J,Salata R M,Tribout M C,Facchetti A,Ratner A M,Marks J T.J Am Chem Soc,2008,130:9679~9694
[12]  19 Konwar D,Boruah R C,and Sandhu J S.Tetrahedron Lett,1990,31(7):1063~1064
[13]  20 Sakamoto T,Mori H,Takizawa M,Kikugawa Y.Synthesis,1991,9:750~752
[14]  21 Meshram H M.Synthesis,1992,10:943~944
[15]  22 Iranpoor N,Zeynizadeh B.Synth Commun,1999,29(16):2747~2752
[16]  23 Barman D C,Thakut A J,Prajapati D,Sandhu J S.Chem Lett,2000,29:1196~1197
[17]  24 Li Y.European patent,EP 2 034 537 A3.2009-06-24
[18]  10 Kularatne R S,Magurudeniya H D,Sista P,Biewer M C,Stefan M C.J Polym Sci A Polym Chem,2013,51:743~768
[19]  11 Song H Y,Tong H,Xie Z Y,Wang L X,Wang F S.Chinese J Polym Sci,2013,31(8):1117~1126
[20]  12 Dou L T,You J B,Yang J,Chen C C,He Y J,Murase S,Moriarty T,Emery K,Li G,Yang Y.Nature Photonics,2012,6:180~185
[21]  13 Qu S Y,Tian H. Chem Commun,2012,48:3039~3051
[22]  14 Ye Huaiying(叶怀英),Li Wen(李 文),Li Weishi(李维实).Chin J Org Chem(有机化学),2012,32:266~283
[23]  15 Zhou Mingjie(周明杰),Wang Ping(王平),Zhang Zhenhua(张振华),Feng Xiaoming(冯小明).China patent,CN201210346674.2012-09-18
[24]  16 Bronstein H,Chen Z,Ashraf R S,Zhang W,Du J,Durrant R J,Tuladhar P S,Song K,Watkins E S,Geerts Y,Wienk M M,Janssen A J R,Anthopoulos T,Sirringhaus H,Heeney H,McCulloch I.J Am Chem Soc,2011,133:3272~3275
[25]  25 Seitz D E,Lee S H,Hanson R N,Bottaro J C.Synth Commun,1983,13:121~128
[26]  26 Haid S,Mishra A,Weil M,Uhrich C,Pfeiffer M,B？uerle P.Adv Funct Mater,2012,22:4322~4333
[27]  27 Faderl J,Deobald B,Guilard R,Pritzkow H,Siebert W.Eur J Inorg Chem,1999,3:399~404
[28]  28 Bronstein H,Collado-Fregoso E,Hadipour A,Soon W Y,Huang Z,Dimitrov D S,Ashraf R S,Rand P B,Watkins E S,Tuladhar S P,Meager I,Durrant R J,McCulloch I.Adv Funct Mater,2013,23:5647~5654

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