OALib Journal期刊
多重点击反应制备拓扑结构聚合物
DOI: 10.3724/SP.J.1105.2014.13434
Keywords: 点击反应 ,多重点击反应 ,拓扑结构聚合物 ,联用 ,活性聚合
Abstract:
点击反应由Sharpless提出，是一类具有高效、可靠、高选择性等特点的反应，被广泛用于各种拓扑结构聚合物的制备.目前，应用较为广泛的点击反应主要有Cu（I）催化的叠氮/炔环加成反应（CuAAC）、Diels-Alder（D-A）反应、巯基-烯及巯基-炔点击反应和氮氧自由基偶合反应.近年来，将多种点击反应结合起来，为高效合成拓扑结构聚合物提供了新的思路.本文综述了近几年来采用多重点击反应策略联用制备拓扑结构聚合物的研究进展，并对其发展趋势进行展望.
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