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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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2-呋喃甲硫醇修饰环糊精形成互锁式螺旋柱状超分子的自组装行为
DOI: 10.6023/A12121070, PP. 439-442
Keywords: 修饰环糊精,2-呋喃甲硫醇,自组装,晶体结构,超分子
Abstract:
利用单-(6-氧-对甲基苯磺酰基)-β-环糊精和2-呋喃甲硫醇反应得到单修饰环糊精,单[6-硫-6-(2-甲基呋喃)]-β-环糊精.通过X-ray衍射分析及核磁光谱等方法研究了其在溶液和固态中形成线状超分子的分子自组装行为.结果表明,化合物在固态中通过呋喃基团从第二面羟基连续插入到另一个环糊精的空腔,形成了互锁式螺旋柱状超分子,而且在溶液中也显示了相似的自组装行为,其键合常数K及聚合度n分别为450mol-1·L和1.9.
| [1] | Liu, Y.; Shi, J.; Chen, Y.; Ke, C.-F. Angew. Chem., Int. Ed. 2008, 47, 7293.
|
| [2] | Zhang, Z.-J.; Zhang, H.-Y.; Wang, H.; Liu, Y. Angew. Chem., Int. Ed. 2011, 50, 10834.
|
| [3] | Guo, D.-S.; Wang, K.; Wang, Y.-X.; Liu, Y. J. Am. Chem. Soc. 2012, 134, 10244.
|
| [4] | Zhang, Z.; Luo, Y.; Chen, J.; Dong, S.; Yu, Y.; Ma, Z.; Huang, F. Angew. Chem., Int. Ed. 2011, 50, 1397.
|
| [5] | Dong, S.; Luo, Y.; Yan, X.; Zheng, B.; Ding, X.; Yu, Y.; Ma, Z.; Zhao, Q.; Huang, F. Angew. Chem., Int. Ed. 2011, 50, 1905.
|
| [6] | Yan, X.-Z.; Wang, F.; Zheng, B.; Huang, F.-H. Chem. Soc. Rev. 2012, 41, 6042.
|
| [7] | Liu, Y.; Zhao, Y.-L.; Zhang, H.-Y.; Song, H.-B. Angew. Chem., Int. Ed. Engl. 2003, 42, 3260.
|
| [8] | Liu, Y.; Yu, Z.-L.; Zhang, Y.-M.; Guo, D.-S.; Liu, Y.-P. J. Am. Chem. Soc. 2008, 130, 10431.
|
| [9] | Duan, W.-S.; Liu, B.; Sun, Z.-G.; Yang, B.-S. Acta Chim. Sinica 2011, 69, 1789. (段文胜, 刘斌, 孙占国, 杨斌盛, 化学学报, 2011, 69, 1789.)
|
| [10] | Shen, H.-M.; Ji, H.-B. Chin. J. Org. Chem. 2012, 32, 975. (沈海民, 纪红兵, 有机化学, 2012, 32, 975.)
|
| [11] | Li, S.-J.; Zhang, X.-J.; Liang, H.-Y.; Wang, X.-R. Acta Chim. Sinica 2012, 70, 1031. (李姝静, 张小军, 梁海燕, 王心蕊, 化学学报, 2012, 70, 1031.)
|
| [12] | Zhu, L.-L.; Yan, H.; Nguyen, K.-T.; Tian, H.; Zhao, Y.-L. Chem. Commun. 2012, 48, 4290.
|
| [13] | Ke, C.-F.; Yang, C.; Mori, T.; Wada, T.; Liu, Y.; Inoue, Y. Angew. Chem., Int. Ed. 2009, 48, 6675.
|
| [14] | Liu, Y.; Ke, C.-F.; Zhang, H.-Y.; Cui, J.; Ding, F. J. Am. Chem. Soc. 2008, 130, 600.
|
| [15] | Wang, H.-S.; Peng, J.-T.; Wei, J.-P.; Jiang, A. Acta Chim. Sinica 2012, 70, 1355. (王怀松, 彭江涛, 魏纪平, 姜安, 化学学报, 2012, 70, 1355.)
|
| [16] | Tang, K.-W.; Li, H.-J.; Liu, Y.-B. Acta Chim. Sinica 2011, 69, 2696. (唐课文, 李洪建, 刘永兵, 化学学报, 2011, 69, 2696.)
|
| [17] | Yang, C.; Ke, C.-F.; Liang, W.-T.; Fukuhara, G.; Mori, T.; Liu, Y. J. Am. Chem. Soc. 2011, 133, 13786.
|
| [18] | Du, P.; Chen, G.-S.; Jiang, M. Sci. China, Ser. B-Chem. 2012, 42, 723. (杜萍, 陈国颂, 江明, 中国科学B辑: 化学, 2012, 42, 723.)
|
| [19] | Zhou, Y.-H.; Mao, Z.-W. Sci. China, Ser. B-Chem. 2009, 39, 289. (周映华, 毛宗万, 中国科学B辑: 化学, 2009, 39, 289.)
|
| [20] | Yan, H.; Teh, C.; Sreejith, S.; Zhu, L.-L.; Kwok, A.; Fang, W.-Q.; Ma, X.; Nguyen, K. T.; Korzh, V.; Zhao, Y.-L. Angew. Chem., Int. Ed. 2012, 51, 8373.
|
| [21] | Zhu, L.-L.; Yan, H.; Zhao, Y.-L. Int. J. Mol. Sci. 2012, 13, 10132.
|
| [22] | Chen, Y.; Liu, Y. Chin. J. Org. Chem. 2012, 32, 805. (陈湧, 刘育, 有机化学, 2012, 32, 805.)
|
| [23] | Zhang, H.-C.; Liu, Z.-N.; An, W.; Hao, A.-Y.; Sun, L.-Z. Chin. J. Org. Chem. 2010, 30, 1279. (张华承, 刘召娜, 安伟, 郝爱友, 孙立臻, 有机化学, 2010, 30, 1279.)
|
| [24] | Jiang, J.-Q.; Chen, X.; Yin, M.; Wang, Z.-P.; Liu, X.-Y.; Chen, M.-Q. Acta Chim. Sinica 2012, 70, 525. (江金强, 陈欣, 殷明, 王周平, 刘晓亚, 陈明清, 化学学报, 2012, 70, 525.)
|
| [25] | Hirotsu, K.; Higuchi, T.; Fujita, K.; Ueda, T.; Shinoda, A.; Imoto, T.; Tabushi, I. J. Org. Chem. 1982, 47, 1143.
|
| [26] | Harata, K. Chem. Rev. 1998, 98, 1803.
|
| [27] | Kamitori, S.; Hirotsu, K.; Higuchi, T.; Fujita, K.; Yamamura, H.; Imoto, T.; Tabushi, I. J. Chem. Soc., Perkin Trans. 2 1987, 7.
|
| [28] | Liu, Y.; You, C.-C.; Zhang, M.; Weng, L.-H.; Wada, T.; Inoue, Y. Org. Lett. 2000, 2, 2761.
|
| [29] | Liu, Y.; Fan, Z.; Zhang, H.-Y.; Yang, Y.-W.; Ding, F.; Liu, S.-X.; Wu, X.; Wada, T.; Inoue, Y. J. Org. Chem. 2003, 68, 8345.
|
| [30] | Zhao, Y.-L.; Liu, Y. Sci. China, Ser. B-Chem. 2006, 49, 230.
|
| [31] | Fan, Z.; Guo, M.-J.; Dong, B.; Diao, C.-H.; Jing, Z.-L.; Chen, X. Sci. China, Ser. B-Chem. 2010, 53, 1089.
|
| [32] | Li, W.-J.; Fan, Z.; Diao, C.-H.; Wang, M. Carbohydr. Res. 2012, 349, 103.
|
| [33] | McAlpine, S. R.; Garcia-Garibay, M. A. J. Am. Chem. Soc. 1998, 120, 4269.
|
| [34] | Harata, K.; Takenaka, Y.; Yoshida, N. J. Chem. Soc., Perkin Trans. 2 2001, 1667.
|
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