OALib Journal期刊
铟-锑系统热力学性质的计算
, PP. 51-58
Abstract:
根据前文中求得的次正规溶体模型运用于同分熔解化合物的关系式,进一步讨论了In-Sb系统的热力学性质。由已经求得的两个次正规常数,计算了InSb化合物的标准形成自由能ΔF_(Insb)~o(T)(以液态组元In和Sb为标准态),并计算了In-Sb平衡图中和InSb化合物处于平衡的液相线,计算结果与实验数据均能良好符合。本文并针算了In-Sb溶液的各热力学函数及组元的活度,和Terpilowski的实验数据作了比较。
References
[1] 田德诚、乐锡熊,金属学报,1965． 1,38． [2] Liu, T. S. (刘天锡), Peretti, E. A.: Trans. Am. Soc. Metals, 1952, 44, 539, (参阅文献 [3] ). [4] 1949, 17, 204, (参阅文献 [5] ). [6] Hansen, M., Anderko, K.: Constitution of Binary Alloys, 2nd ed., (McGraw-Hill, 1958) , p. 858． [7] Schottky, W. F., Bever, M. B.: Acta Met., 1958, 6, 320． [8] Terpilowski, J.: Arch. Hutnictwa, 1959, 4, 369． [9] Bednar, J., Smirous, K.: Czech. J. Phys., 1955, 5, 546． [10] #12 [11] Terpilowski, J., Tzebiatowski, W.: Bull. Acad. Polon. Sci., Ser. Sci. Chim., 1960, 8, 95． [12] Kelley, K. K.: Contributions to the Data on Theoretical Metallurgy XIII. High Temperature Heat-Content, Heat-Capacity, and Entropy Data for the Elements and Inorganic Compounds, (U. S. Bureau of Mines, Bull. No. 584, 1960) , p. 15． [13] #12
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