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金属学报  1980 

LaNi_5吸氢过程动力学的研究

, PP. 65-72

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Abstract:

在初始压力15—30atm、温度20—85℃的范围内研究了储氢材料LaNi_5在恒温时吸氢的动力学过程.实验结果表明吸氢量与时间的对数呈线性关系;吸氢速率随初始压力的提高或吸氢温度的升高而改变.提出了表示吸氢速率对时间、初始压力、吸氢温度依赖性的关系式,实验结果与之一致.按这一关系式可以得到吸氢速率的限制性环节的激活能U.在吸氢量(以饱和度计)约70%以前,U约为2.0kcal/molH_2,吸氢量更高时约3.2kcal/molH_2.这些数据为进一步确定吸氢速率的限制性环节提供了重要参数.

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