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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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冶金熔体热力学的若干研究
, PP. 127-140
Abstract:
为了从二元系中两组元活度的测定值之比求得该两组元的活度值,导出了一个变通的Gibbs-Duhem方程式,并在PbCl_2-SnCl_2,PbCl_2-CdCl_2,AgCl-CuCl,Cu_2S-FeS,PbO-BiO_(1.5),PbO-SbO_(1.5),CaO-CaF_2及CaO-SiO_2-CaF_2等冶金熔体中得到应用.多年前所发展的从Ag和Pb二元相图求得两组元活度的方法已扩大到含有单个AB化合物的二元系.用这一方法已求得In-Sb和Sn-Te系中各组元的活度.在研究某些黑色冶金渣与金属间的平衡时,用一适当选择的非铁金属代替Fe作为熔剂金属有助于克服某些实验上的困难.采用Sn或Cu与熔渣平衡研究了CaO-SiO_2,CaO-Al_2O_3和CaO-SiO_2-Al_2O_3体系.对CaO-SiO_2二元系获得的数据可以认为具有足够的准确度来验证Masson模型的合理性.
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