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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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LiF-CaF_2,NaF-CaF_2和KF-CaF_2系熔体热力学参量及相图的计算
, PP. 150-155
Keywords: ＬｉＦ－ＣａＦ_２,ＮａＦ－ＣａＦ_２,ＫＦ－ＣａＦ_２,ＤＣＡ模型,熔体热力学性质,熔盐相图
Abstract:
本文将ＤＣＡ模型应用于ＬｉＦ－ＣａＦ２，ＮａＦ－ＣａＦ２和ＫＦ－ＣａＦ２熔体，并假设在这些熔体中存在络合离子．利用已有的上述混合熔体量热和熔盐相图的实验数据估计了熔体模型中的参数，并计算了熔体的混合热力学参量及相图．计算结果与实验结果吻合较好．
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