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金属学报  1998 

用活度相互作用系数描述多元体系热力学

, PP. 753-762

Keywords: 热力学,活度,模型

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Abstract:

基于MacLaurin级数推出了可用于同时计算烙体中溶质和溶剂活度系数的解析表达式,其特点是保留了热力学的一致性,且比传统的Wagnerε公式更精确.另外,在本文研究的体系内,高阶活度相互作用系数对体系的热力学性质影响很小

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