|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
Cu在熔融（Li,K）2CO3中的热腐蚀行为研究
, PP. 623-626
Keywords: 热腐蚀,电化学阻抗谱,铜,碳酸钾,碳酸锂
Abstract:
采用电化学阻抗谱技术研究了Ｃｕ在６５０℃熔融（Ｌｉ,Ｋ）２ＣＯ２中的腐蚀行为,在腐蚀初期,Ｃｕ的腐蚀的电化学阻抗谱呈典型的腐蚀反应受氧化剂粒子扩散控制的特征,随着腐蚀的进行,在Ｃｕ的表在逐渐形成了Ｃｕ２Ｏ膜,但同时,生成的Ｃｕ２Ｏ也发生溶解,使Ｃｕ局部遭受较快腐蚀,其电化学阻抗谱呈双抗弧特征,提出了相应的等效电路,并求取了相关电化学参数.
| [1] | DDoi K,Yoshida T,Segawa T.Fuel Cell Seminar,Phoenix, 1990:83
|
| [2] | DDu S L, Lu H D, Lu L Q. Chem Ind Eng Progr, 1994; 1: 29 (杜森林,卢洪德,路连清.化工进展,1994;1:29)
|
| [3] | SShores D A,Sing P. Proc Electrochem Soc,1984;84:271
|
| [4] | SSpiegel M, Biedenkopf P, Grabke H J. Corros Sci, 1997; 39: 1193
|
| [5] | HHara M, Shinata Y, Hashimoto S. Corros Sci, 1997; 39: 627
|
| [6] | VVossen J P T;Plomp L,Wit J H W.J Electrochem Soc, 1994; 141: 3040
|
| [7] | NNumata H,Nakasaki O,Ohno I, Harugama S.Corros Eng,1991;40:110(沼田博雄,若崎修,大野泉,春山志郎.材料与环境,1991;40:110)
|
| [8] | CChien-Tung L, Owen F D.J Electrochem Soc, 1991; 138: 386
|
| [9] | ZZeng C L, Zhang J Q, Niu Y, Wu W T. Chin Sci Bull, 1994;39:1190(曾潮流,张鉴清,牛焱,吴维.科学通报,1994;39:1190)
|
| [10] | Niu Y.Zhang J Q,Wu W T.J Chin Soc Crros Protect,1990; 10:221 (牛焱,张鉴清,吴维.中国腐蚀与防护学报,1990;10:221)
|
| [11] | Wang J,Shi C Y,Song S Z.J Chin Soc Corros Protect,1989; 9:12 (王佳,施存余,宋诗哲.中国腐蚀与防护学报,19892 9:12)
|
| [12] | smith S W,Vogel W M,Kapelmer S.J Electrochem Soc, 1982; 129:1668
|
| [13] | Nishina T,Uchidal,Selman J R.J Electrochem Soc,1994;141:1191
|
| [14] | Rapp R A,Goto K S.In:Braunstein J,Selman J R eds., Molten Salts,Pennington,New Jersey:Electrochem Society,1981:81A
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
