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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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高强铝合金裂纹尖端在3.5NaCl溶液中的微区电化学特性
DOI: 10.3724/SP.J.1037.2011.00692, PP. 414-419
Keywords: 2024-T351铝合金,毛细管微电极,扫描Kelvin探针,微区电化学,裂纹尖端
Abstract:
采用毛细管微电极测试方法、扫描Kelvin探针技术和数值分析方法,对2024-T351高强铝合金裂纹尖端在3.5NaCl溶液中的微区电化学特性和腐蚀行为进行了研究.结果表明,裂纹尖端的腐蚀电位较远离裂纹尖端的基体位置更负,裂纹尖端处的电化学活性明显增加.在外加应力的作用下,裂纹尖端处表面氧化膜的厚度减薄,其稳定性和保护性变弱.裂纹尖端处优先发生阳极溶解,浸泡24h后在裂纹尖端处出现腐蚀产物的堆积.由于腐蚀电位和电化学活性的差异,在裂纹尖端(阳极)和远离裂纹尖端的基体(阴极)之间可形成电偶对,进一步促进裂纹尖端局部区域内腐蚀过程的进行.
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