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化学进展 2001

甲烷单加氧酶的催化反应机理研究*

陈建波,夏春谷,辛嘉英,崔俊儒,李树本

Keywords: 甲烷单加氧酶,反应机理,中间化合物

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Abstract:

本文就甲烷单加氧酶近年来在催化反应机理方面的最新研究成果进行了详细阐述。甲烷C—H键的活化机理主要包括自由基回弹机理和协调的氧插入机理。运用自由基探针底物和量化计算等方法对烷烃羟基化反应机理的直接研究表明,目前没有一个统一的机理来解释甲烷单加氧酶的反应过程。反应机理的类型可能取决于MMO的来源或者其他因素。对甲烷单加氧酶的几种中间化合物的各种光谱学研究有力地推动了机理研究的发展。

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