|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
均相催化氧化中的活性中间体多样性
, PP. 203-211
Keywords: 催化氧化,活性中间体,反应活性异同性
Abstract:
过渡金属离子在各种化学及生物氧化中扮演着极为重要的作用,现有的研究表明参与催化氧化的关键活性物种已不再局限于金属氧物种(Mn+O),金属氢氧物种(Mn+—OH)与金属过氧物种(Mn+—OOH)均被发现能够参与各种氧化反应。有些有机化合物也能直接催化有机物的氧化反应,同时,相似的有机物如NADH和辅酶Q一直在生物代谢中发挥着重要作用。但是,现有的研究结果还难以清楚解释生物体系中各种氧化酶在不同的氧化反应中选择特定活性物种的内在原因。因此,了解这些活性物种之间的氧化性能异同性将非常有助于了解酶对它们的选择,进而理解酶的催化氧化机理,为药物设计提供理论基础,同时也有助于设计新的氧化催化剂。本文对在各种均相催化氧化及生物氧化反应中出现的主要活性中间体种类、各中间体的反应性能、反应机理进行了总结,并就现有的实验数据对过渡金属氧物种与氢氧物种的氧化性能相似性及相异性进行了初步评述。
| [1] | Katsuki T, Sharpless K B. J. Am. Chem. Soc., 1980, 102: 5974-5976
|
| [2] | Groves J T, Lee J, Marla S S. J. Am. Chem. Soc., 1997, 119: 6269-6273
|
| [3] | Meunier B, de Visser S P, Shaik S. Chem. Rev., 2004, 104: 3947-3980
|
| [4] | Stockert A L, Shinde S S, Anderson R F, Hill R. J. Am. Chem. Soc., 2002, 124: 14554-14555
|
| [5] | Goldsmith C R, Stack T D P. Inorg. Chem., 2006, 45: 6048-6055
|
| [6] | Goldsmith C R, Cole A P, Stack T D P. J. Am. Chem. Soc., 2005, 127: 9904-9912
|
| [7] | Yin G, Danby A M, Kitko D, Carter J D, Scheper W M, Busch D H. J. Am. Chem. Soc., 2008, 130: 16245-16253
|
| [8] | Toy P H, Newcomb M, Coon M J, Vaz A D N. J. Am. Chem. Soc., 1998, 120: 9718-9718
|
| [9] | Namuswe F, Kasper G D, Sarjeant A A N, Hayashi T, Krest C M, Green M T, Monne-Loccoz P, Goldberg D P. J. Am. Chem. Soc., 2008, 130: 14189-14200
|
| [10] | Yin G, Buchalova M, Danby A M, Perkins C M, Kitko D, Carter J D, Scheper W M, Busch D H. J. Am. Chem. Soc., 2005, 127: 17170-17171
|
| [11] | Yin G, Buchalova M, Danby A M, Perkins C M, Kitko D, Carter J D, Scheper W M, Busch D H. Inorg. Chem., 2006, 45: 3467-3474
|
| [12] | Yin G, Danby A M, Kitko D, Carter J, Scheper W, Busch D. Inorg. Chem., 2007, 46: 2173-2180
|
| [13] | Lee S H, Xu L, Park B K, Mironov Y V, Kim S H, Song Y J, Kim C, Kim Y, Kim S K. Chem. A Euro. J., 2010, 16: 4678-4685
|
| [14] | De Boer J W, Browne W R, Brinksma J, Alsters P L, Hage R, Feringa B L. Inorg. Chem., 2007, 46: 6353-6372
|
| [15] | Mikael T, Jerker O, Gustav D. Biochimica et Biophysica Acta, 2004, 1660: 171-199
|
| [16] | Dijksman A, Marino-Gonzalez A, Mairata P A, Arends I W C E, Sheldon R A. J. Am. Chem. Soc., 2001, 123: 6826-6833
|
| [17] | Zhang W, Ma H, Zhou L, Sun Z, Du Z, Miao H, Xu J. Molecules, 2008, 13: 3236-3245
|
| [18] | Yin G, Danby A M, Kitko D, Carter J D, Scheper W M, Busch D H. J. Am. Chem. Soc., 2008, 130: 16245-16253
|
| [19] | Kurahashi T, Kikuchi A, Tosha T, Shiro Y, Kitagawa T, Fujii H. Inorg. Chem., 2008, 47: 1674-1686
|
| [20] | Fiedler A T, Que L. Inorg. Chem., 2009, 48: 11038-11047
|
| [21] | Xu A, Xiong H, Yin G. Chem. Eur. J., 2009, 15: 11478-11481
|
| [22] | Behan R K, Green M T. J. Inorg. Biochem., 2006, 100: 448-459
|
| [23] | Groves J T. J. Chem. Edu., 1985, 62: 928-931
|
| [24] | Zhang W, Loebach J L, Wilson S R, Jacobsen E N. J. Am. Chem. Soc., 1990, 112: 2801-2803
|
| [25] | Periana R A, Taube D J, Gamble S, Taube H, Satoh T, Fujii H. Science, 1998, 2800: 560-564
|
| [26] | Hay A S, Balnchard H S. Can. J. Chem., 1965, 43: 1306-1317
|
| [27] | Stone K L, Behan R K, Green M T. Proc. Nat. Acad. Sci. USA, 2006, 103: 12307-12310
|
| [28] | Solomon E I, Zhou J, Neese F, Pave1 E G. Chem. Biol., 1997, 4: 795-808
|
| [29] | Hamberg M, Oliw H, Su C. J. Biol. Chem., 1998, 273: 13080-13088
|
| [30] | Yin G, Danby A M, Kitko D, Carter J D, Scheper W M, Busch D H. J. Am. Chem. Soc., 2007, 129: 1512-1513
|
| [31] | Fiedler A T, Que L. Inorg. Chem., 2009, 48: 11038-11047
|
| [32] | Nam W, Ho R, Valentine J S. J. Am. Chem. Soc., 1991, 113: 7052-7054
|
| [33] | Payeras A M, Ho R Y N, Fujita M, Que L. Chem. Eur. J., 2004, 10: 4944-4953
|
| [34] | Jiang Y, Telser J, Goldberg D P. Chem. Commun., 2009, 6828-6830
|
| [35] | Haras A, Ziegler T. Can. J. Chem., 2009, 87: 33-38
|
| [36] | Ottenbacher R V, Bryliakov K P, Talsi E P. Inorg. Chem., 2010, 49: 8620-8628
|
| [37] | Leeladee P, Goldberg D P. Inorg. Chem., 2010, 49: 3083-3085
|
| [38] | Xu A, Xiong H, Yin G. J. Phys. Chem. A, 2009, 113: 12243-12248
|
| [39] | Stryer L. Biochemistry, 3rd ed. New York: W H Freeman, 1988. Chapter 17
|
| [40] | Tu Y, Wang Z, Shi Y. J. Am. Chem. Soc., 1996, 118: 9806-9807
|
| [41] | Liu R, Liang X, Dong C, Hu X. J. Am. Chem. Soc., 2004, 126: 4112-4113
|
| [42] | Yang G, Ma Y, Xu J. J. Am. Chem. Soc., 2004, 126: 10542-10543
|
| [43] | Yang G, Zhang Q, Miao H, Tong X, Xu J. Org. Lett., 2005, 7: 263-266
|
| [44] | Tong X, Xu J, Miao H. Adv. Syn. Cata., 2005, 347: 1953-1957
|
| [45] | Tong X, Xu J, Miao H, Gao J. Tetrahedron Lett., 2006, 47: 1763-1766
|
| [46] | Sheldon R A, Arends I W C E, Brink G T, Dijksman A. Green Acc. Chem. Res., 2002, 35: 774-781
|
| [47] | Anelli P L, Biffi C, Montanari F, Quici S. J. Org. Chem., 1987, 52: 2559-2562
|
| [48] | Yin G, Danby A M, Kitko D, Carter J D, Scheper W M, Busch D H. J. Am. Chem. Soc., 2007, 129: 1512-1513
|
| [49] | Kurahash T, Kikuchi A, Shiro Y, Hada M, Fujii H. Inorg. Chem., 2010, 49: 6664-6672
|
| [50] | Shi S, Wang Y, Xu A, Zhu D, Roy S B, Jackson T A, Busch D H, Yin G. Angew. Chem. Int. Ed., 2011, 50: 7321-7324
|
| [51] | Ortiz de Montellano P R Ed. Cytochrome P450: Structure, Mechanism, and Biochemistry. New York: Plenum Press, 1986
|
| [52] | Hersleth H, Ryde U, Rydberg P, G？rbitz C H, Andersson K K. J. Inorg. Biochem., 2006, 100: 460-476
|
| [53] | De Boer J W, Brinksma J, Browne W R, Meetsma A, Alsters P L, Hage R, Feringa B L. J. Am. Chem. Soc., 2005, 127: 7990-7991
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
