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OALib Journal期刊
ISSN: 2333-9721
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金属-有机骨架材料在烯烃氧化中的应用
, PP. 747-756
Keywords: 金属有机骨架,氧化,烯烃,环氧化,催化
Abstract:
本文分别从以骨架中的金属(金属簇)为催化中心的MOF材料、利用具有催化活性的刚性有机配合物构筑的MOF材料和MOF负载催化材料三个方面详细介绍了MOF作为催化剂在烯烃氧化反应中的应用情况,分析了其各自的优缺点。具有催化活性的刚性有机配合物构筑的MOF材料稳定性较好,能够引入具有光学活性的催化剂,可以作为不对称催化氧化催化剂使用,是未来的一个研究发展方向。
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