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化学进展  2012 

生物及化学反硝化过程中N2O的产生与控制

, PP. 2054-2061

Keywords: N2O,脱氮,反硝化,Fe(Ⅱ),NH4+

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Abstract:

长期以来,人们都将N2O视为一种温室气体,然而事实上N2O在航天领域是一种宝贵的能源物质,西方发达国家对N2O的制备技术相当重视。生物及化学反硝化过程都能产生大量的N2O,但将N2O作为能源气体收集利用在我国还未受到重视。本文介绍了国内外关于污水脱氮过程中N2O生成情况的研究,分析了生物脱氮过程中N2O的产生机理和影响因素,同时探讨了化学反硝化作用,尤其是Fe(Ⅱ)的还原作用对N2O生成和控制的影响,提出了对N2O进行资源化利用的途径。最后指出,可以大量积累N2O的化学反硝化过程应是今后水体脱氮的重要研究方向,尤其是化学反硝化过程中N2O的产生机理和影响因素值得进一步研究。

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