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化学进展  2013 

高温共电解H2O/CO2制备清洁燃料

DOI: 10.7536/PC121149, PP. 1229-1236

Keywords: 高温共电解,固体氧化物电解池,CO2减排,清洁燃料

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Abstract:

高温共电解(hightemperatureco-electrolysis,HTCE)H2O和CO2技术是一种很有前景的清洁燃料制备和CO2减排新技术。该技术可利用可再生能源或核能提供的电能和高温热,通过高温固体氧化物电解池(solidoxideelectrolysiscell,SOEC)将H2O和CO2共电解生产合成气(H2+CO),再将制备的合成气用于生产各种液态碳氢燃料。本文详细介绍了利用高温固体氧化物电解池共电解H2O和CO2制备合成燃料的基本原理、发展历程和目前世界各国的研究进展,对该技术的优势和特点进行了分析,并对该技术在关键材料、反应机理等方面存在的问题进行了总结和讨论,最后对其在新能源技术领域的应用前景作了展望。

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