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OALib Journal期刊
ISSN: 2333-9721
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含单质硫正极复合材料
DOI: 10.7536/PC130310, PP. 1867-1875
Keywords: 锂-硫电池,单质硫,碳材料,导电聚合物,氧化物
Abstract:
单质硫作为二次锂-硫电池正极时具有很高的理论比容量(1675mAh/g),此外硫原料廉价、储量丰富、对环境友好,被认为是最具发展潜力的新一代高比能化学电源的正极材料之一。但由于单质硫存在导电性差以及充放电过程中体积膨胀,放电过程中产生的多硫离子会溶解发生扩散迁移,从而制约了锂-硫电池的进一步发展应用。本文首先分析了锂-硫电池的放电机理,以及导致电池容量衰减的两个主要原因多硫离子的穿梭效应和放电产物硫化锂(Li2S,Li2S2)差的电化学性能;其次综述了近年来国内外报道的各种含硫复合材料,将其分为碳/硫复合材料、导电聚合物/硫复合材料、氧化物/硫复合材料三大类,并进行了讨论;最后总结了目前硫正极复合材料的特点,展望了含单质硫复合正极材料未来的研究发展趋势。
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