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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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锂离子电池高电压电解液
DOI: 10.7536/PC130816, PP. 553-559
Keywords: 锂离子电池,高电压电解液,添加剂,理论计算
Abstract:
开发高电压正极材料是发展高能量密度锂离子电池的重要途径之一。常规电解液在高电压下容易与正极材料表面发生副反应，影响高电压正极材料性能的发挥，因此，高电压电解液引起了人们广泛的关注。本文主要从新型溶剂体系和常规碳酸酯溶剂体系两方面对锂离子电池高电压电解液进行综述与评价，提出了现有电解液的不足及面临的问题。从电解液溶剂分子设计理论入手，分析了砜类溶剂、腈基溶剂和离子液体等新型溶剂作为高压电解液溶剂的优缺点，同时探讨了不同种类添加剂在常规碳酸酯溶剂体系中的作用机理。此外，本文还介绍了理论计算方法在锂离子电池高电压电解液研究中的应用，并对其在设计新型高电压电解液中的应用前景进行了展望。
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