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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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含氮杂环结构的阻燃环氧树脂基电子材料
DOI: 10.7536/PC131043, PP. 1021-1031
Keywords: 环氧,阻燃,氮杂环,无卤,无铅,无磷
Abstract:
“无卤无磷无铅”的绿色阻燃环氧树脂基电子材料是既能满足阻燃功能、又需符合环保要求的热固性（复合）材料，是目前阻燃热固性树脂领域的重点和难点课题。有机氮杂环作为一类高效、低毒的阻燃结构，可以共价引入至环氧树脂中，但至今还未建立系统的氮杂环的结构与其阻燃性能的关系。本文结合本课题组近十年的研究工作，综述了近年来国内外含氮杂环阻燃环氧树脂的研究进展，讨论了不同含氮杂环结构（三嗪环、异氰脲酸酯环、二氮杂萘酮、酰亚胺、苯并NFDA1嗪和海因环等）环氧树脂固化物的制备方法，给出了定量的结构与性能关系。利用共价键法将含氮杂环结构引入环氧树脂体系中，在实现阻燃功能的同时也能保持材料的综合性能，甚至可提高环氧树脂固化物的热稳定性能，因而制备含氮杂环结构的环氧树脂是“无卤无磷无铅”绿色阻燃的重要解决方案。但是，目前仅依靠含氮杂环结构很难达到理想阻燃效果，大部分已报道的体系只能达到“无卤无铅少磷”的水平，仍需要进一步深入研究和认识含氮杂环结构的阻燃环氧体系的结构-性能关系，并提出提高含氮杂环体系阻燃效果可能的解决方法。
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