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化学进展 2014

单个量子点的光学性质与应用

DOI: 10.7536/PC140739, PP. 1781-1792

石星波,温超,符招弟,邓放明,郑舒,刘秋云

Keywords: 单个量子点,荧光增强与漂白,光谱蓝移,生物传感,超分辨定位,单分子示踪

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Abstract:

量子点(QDs)是一种具有诸多优良光学特性的荧光纳米颗粒,已在化学分析、生物传感、分子影像等领域得到了广泛应用.单个量子点的光学性质研究有望发现一些宏观方法不能发现的实验现象,可以为改善其光学性能提供思路,有助于更好的应用于各领域.本文评述了单个量子点的检测与判定方法,单个量子点的荧光增强、漂白、眨眼(blinking)、蓝移等光学性质及其在单分子示踪、生物化学传感、超分辨定位技术等方面的应用.总结了目前量子点作为荧光探针在实际应用中遇到的问题,并提出未来量子点将朝着合成能同时满足尺寸小、量子产率高、"non-blinking"、蓝移幅度大、无生物毒性的量子点及能同时为成像/检测提供荧光探针与散射探针的等离子体量子点等研究方向发展.

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