|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
离子型膦配体及其离子型过渡金属配合物的合成和均相催化作用
DOI: 10.7536/PC140813, PP. 27-37
Keywords: 离子型膦配体,离子型过渡金属配合物,均相催化,离子液体
Abstract:
与传统中性叔膦配体构建的过渡金属配合物相比,由离子型膦配体配位构建的过渡金属配合物具有典型的离子盐组成特点、独特的电子效应和几何构型。该类配合物中,不仅存在金属和配体间的配位作用,还存在正电荷的强吸电子效应和阴阳离子的静电作用,由此可以产生独特的催化性能。近年来,离子型过渡金属配合物的合成及其均相催化应用成为配位化学和均相催化研究中备受关注的领域。离子型过渡金属配合物的离子盐结构,使其在与室温离子液体溶剂结合使用时,离子型离子配体及其配合物能够严格被锁定在离子液体相,具有避免离子型离子配体及其配合物的流失、抑制其失活、并实现循环使用的优点,也成为均相催化固载化的绿色方法之一。本文综述了近十年发展的一类咪唑鎓基与膦配体中的磷原子毗邻的离子型膦配体的合成,及其相应Rh、Pd、Ru、Pt、Au、Ni、Cu等离子型配合物的构建,并介绍了它们在均相催化反应中的应用。
| [1] | Colby D A, Bergman R G, Ellman J A. Chem. Rev., 2010, 110 (2): 624.
|
| [2] | Li Z, Brouwer C, He C. Chem. Rev., 2008, 108 (8): 3239.
|
| [3] | Franke R, Selent D, B？rner A. Chem. Rev., 2012, 112: 5675.
|
| [4] | Sakai N, Mano S, Nozaki K, Takaya H. J. Am. Chem. Soc., 1993, 115: 7033.
|
| [5] | Fielder S S, Osborne M C, Lever A B P, Pietro W J. J. Am. Chem. Soc., 1995, 117: 6990.
|
| [6] | Yan Y, Chi Y, Zhang X. Tetrahedron: Asymm., 2004, 15: 2173.
|
| [7] | Tricas H, Diebolt O, van Leeuwen P W N M. J. Catal., 2013, 298: 198.
|
| [8] | Ellis B D, Ragogna P J, Macdonald C L B. Inorg. Chem., 2004, 43: 7857.
|
| [9] | Bronger R P J, Silva S M, Kamer P C J, van Leeuwen P W N M. Dalton Trans. 2004, 1590.
|
| [10] | Andrieu J, Azouri M. Inorg. Chim. Acta, 2007, 360: 131.
|
| [11] | Dunbar K R, Haefner S C. Inorg. Chem., 1992, 31 (17): 3676.
|
| [12] | Christoph G G, Halperk J, Khare G P, Koh Y B, Romanowski C. Inorg. Chem., 1981, 20: 3029.
|
| [13] | Burgess K, van der Donk W A, Westcott S A, Marder T B, Baker R T, Calabrese J C. J. Am. Chem. Soc., 1992, 114: 9350.
|
| [14] | Kuhn N, Fahl J. Z. Anorg. Allg. Chem., 1999, 625: 729.
|
| [15] | Kuhn N, G？hner M. Z. Anorg. Allg. Chem., 1999, 625: 1415.
|
| [16] | Kuhn N, G？hner M, Steimann M. Z. Anorg. Allg. Chem., 1999, 628: 896.
|
| [17] | Azouri M, Andrieu J, Picquet M, Cattey H. Inorg. Chem., 2009, 48 : 1236.
|
| [18] | Brunet J J, Chauvin R, Commenges G, Donnadieu B, Leglaye P. Organometallics, 1996, 15 : 1752.
|
| [19] | Cadierno V, Francos J, Gimeno J. Chem. Eur. J., 2008, 22 : 6601.
|
| [20] | Chauvin R. Eur. J. Inorg. Chem., 2000, 577.
|
| [21] | Brauer D J, Kottsieper K W, Liek C, Stelzer O, Waffenschmidt H, Wasserscheid P. J. Organomet. Chem., 2001, 630: 177.
|
| [22] | 尤洪星(You H X), 王永勇(Wang Y Y), 王雪珠(Wang X Z), 刘 晔(Liu Y). 化学进展(Progress in Chemistry), 2013, 25(10):1656.
|
| [23] | Miao W, Chan T H. Acc. Chem. Res., 2006, 39 (12): 897.
|
| [24] | Wu X F, Neumann H, Beller M. Chem. Rev., 2013, 113 (1): 1.
|
| [25] | Vougioukalakis G C, Grubbs R H. Chem. Rev., 2010, 110 (3): 1746.
|
| [26] | Abdellah I, Lepetit C, Canac Y, Duhayon C, Chauvin R. Chem. Eur. J., 2010, 16: 13095.
|
| [27] | Tolmachev A A, Yurchenko A A, Merculov A S, Semenova M G, Zarudnitskii E V, Ivanov V V, Pinchuk A M. Heteroatom Chem., 1999, 10: 585.
|
| [28] | Jalil M A, Yamada T, Fujinami S, Honjo T, Nishikawa H. Polyhedron, 2001, 20: 627.
|
| [29] | Li J, Peng J, Bai Y, Zhang G, Lai G, Li X. J. Organomet. Chem., 2010, 695(3): 431.
|
| [30] | Azouri M, Andrieu J, Picquet M, Richard P, Hanquet B, Tkatchenko I. Eur. J. Inorg. Chem., 2007, 4877.
|
| [31] | Debono N, Canac Y, Duhayon C, Chauvin R. Eur. J. Inorg. Chem., 2008, 2991.
|
| [32] | Canac Y, Debono N, Vendier L, Chauvin R. Inorg. Chem., 2009, 48(12): 5562.
|
| [33] | Barthes C, Lepetit C, Canac Y, Duhayon C, Zargarian D, Chauvin R. Inorg. Chem., 2013, 52: 48.
|
| [34] | Maaliki C, Lepetit C, Canac Y, Bijani C, Duhayon C, Chauvin R. Chem. Eur. J., 2012, 18(25): 7705.
|
| [35] | Andrieu J, Azouri M, Richard P. Inorg. Chem. Commun., 2008, 11: 1401.
|
| [36] | Moloy K G, Petersen J L. J. Am. Chem. Soc., 1995, 117: 7696.
|
| [37] | Wu M L, Desmond M J, Drago R S. Inorg. Chem., 1979, 18: 679.
|
| [38] | Andrieu J, Camus J M, Richard P, Poli R, Gonsalvi L, Vizza F, Peruzzini M. Eur. J. Inorg. Chem., 2006, 51.
|
| [39] | Boyd S E, Field L D, Hambley T W, Partridge M G. Organometallics, 1993, 12: 1720.
|
| [40] | Chen S, Wang Y, Yao W, Zhao X, VO-Thanh G, Liu Y. J. Mol. Catal. A, 2013, 378: 293.
|
| [41] | You H, Wang Y, Zhao X, Chen S, Liu Y. Organometallics, 2013, 32: 2698.
|
| [42] | Brink A, Roodt A, Steyl G, Visser H G. Dalton Trans., 2010, 39: 5572.
|
| [43] | Bennett M J, Donaldson P B. Inorg. Chem., 1977, 16: 655.
|
| [44] | Marion N, Navarro O, Mei J, Stevens E D, Scott N M, Nolan S P. J. Am. Chem. Soc., 2006, 128: 4101.
|
| [45] | Fitton P, Johnson M P, McKeon J E. J. Chem. Soc. Chem. Commun., 1968, 6.
|
| [46] | Canac Y, Debono N, Lepetit C, Duhayon C, Chauvin R. Inorg. Chem., 2011, 50 (21): 10810.
|
| [47] | Zhang J, ?akovi D? M, Popovi D? Z, Wu H, Liu Y. Catal. Commun., 2012, 17: 160.
|
| [48] | Zhou C, Zhang J, Aakovic M, Popovic Z, Zhao X, Liu Y. Eur. J. Inorg. Chem., 2012, 3435.
|
| [49] | Saleh S, Fayad E, Azouri M, Hierso J C, Andrieu J, Picquet M. Adv. Synth. Catal., 2009, 351: 1621.
|
| [50] | Wang X, Wang Y, Zhang J, Zhao X, Liu Y. J. Organomet. Chem., 2014, 762: 40.
|
| [51] | Baenziger N C, Bennett W E, Soborofe D M. Acta Crystallogr., 1976, 32: 962.
|
| [52] | Digard E, Andrieu J, Cattey H. Inorg. Chem. Commun., 2012, 25: 39.
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
