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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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有序分子组装膜电极非理想伏安图的理论研究*
, PP. 821-827
Keywords: 分子间作用,电化学,自组装单层,理论模型,重组能
Abstract:
在有序分子组装体系的电化学研究中，电活性物种间的相互作用直接导致其偏离理想的电化学行为，譬如出现双峰或者峰展宽的现象。从这些非理想的电化学数据中提取热力学和动力学数据显得相对困难，因而了解和评价这些非理想的电化学行为显得十分有必要。本文着重就这些非理想电化学现象的理论模型、基本公式和微观认识进行了评述。理解这些非理性电化学的影响因素，不仅加深对表面电化学体系的认识，更对现在的研究热点课题如主客体识别、分子电子器件、生物传感器等具有重要意义。
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