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OALib Journal期刊
ISSN: 2333-9721
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烯烃易位聚合制备遥爪聚合物及嵌段共聚物
DOI: 10.7536/PC150314, PP. 1074-1086
Keywords: 烯烃易位聚合,遥爪聚合物,非环二烯易位,开环易位聚合,嵌段共聚物
Abstract:
遥爪聚合物因其聚合物链的两端带有反应性官能团,可用于制备嵌段、接枝、星形、超支化等具有特殊结构的聚合物,其制备方法主要包括传统自由基聚合与可控/“活性”自由基聚合、阴离子聚合、阳离子聚合、易位聚合和缩合聚合等。相比于其他的传统聚合方法,烯烃易位聚合是一种较为温和的、产物分子量及结构可控的聚合方法。本文主要概述在各种链转移剂的存在下,采用环烯烃的开环易位聚合(ring-openingmetathesispolymerization,ROMP)和非环二烯易位(acyclicdienemetathesis,ADMET)聚合制备带有各种官能团的遥爪聚合物以及与其他活性聚合方法(NMRP、ATRP、RAFT、ROP等)相结合制备嵌段共聚物的研究进展。
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