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OALib Journal期刊
ISSN: 2333-9721
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[60]富勒烯衍生物的对称性、碳笼结构与13CNMR谱*
Keywords: [60]富勒烯衍生物,13C,NMR,结构表征,对称性
Abstract:
本文全面综述了多种[60]富勒烯衍生物的结构,阐述了(13)~CNMR谱在[60]富勒烯衍生物结构表征中的应用,重点讨论了不同对称性[60]富勒烯衍生物的(13)~CNMR谱图特征.通过[60]富勒烯部分(13)~C共振线的化学位移、数目和相对强度,可以确定[60]富勒烯衍生物的对称结构和加成方式.对于C_s、C_(2v)和C_(3v)对称性的[60]富勒烯衍生物,镜面上的碳原子的相对化学位移很大程度上取决于他们距加成位置的距离.因此,(13)~CNMR谱在碳笼具体结构的确定中具有不可替代的作用.
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