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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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低温制备掺杂氧化锆/氧化铈电解质
, PP. 470-476
Keywords: 固体氧化物燃料电池(SOFC),电解质,烧结曲线,低温
Abstract:
固体氧化物燃料电池(SOFC)及其组元的低温制备有利于材料和电池性能的优化,降低制备成本。立方相的全致密氧化钇稳定氧化锆(YSZ)电解质是SOFC中最通用的电解质。传统的烧结工艺需要在1400—1450℃才能实现YSZ电解质的致密,而使用纳米粉体和三步烧结工艺可以在1200—1300℃得到致密电解质。氧化钪稳定氧化锆(ScSZ)电解质可以使用3nm的粉体在900℃下致密化,氧化钆掺杂的氧化铈可以通过加入烧结助剂在800℃下实现致密化烧结,这些工艺已广泛用于SOFC制备。SOFC的低温制备工艺可有效推进SOFC的产业化。
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