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化学进展  2011 

卟啉-富勒烯络合物的合成

, PP. 1123-1136

Keywords: 卟啉,富勒烯,合成,环加成反应

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Abstract:

按照卟啉与富勒烯连接方式的不同,卟啉-富勒烯化合物可分为共价键连接和非共价键连接两种类型。共价键连接的卟啉-富勒烯化合物主要是通过环加成反应来合成,如1,3-偶极环加成反应、Diels-Alder环加成反应和Bingel-Hirsch环加成反应;非共价键连接的卟啉-富勒烯化合物主要是通过金属的轴向配位及氢键得到。本文综述了近年来不同类型的卟啉-富勒烯化合物的合成研究,着重介绍了共价键连接卟啉-富勒烯化合物的合成及应用前景,分析目前在合成方法上存在的问题,并对未来的研究提出了展望。

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