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化学进展  2011 

可充镁电池电解液

, PP. 1598-1610

Keywords: 可充镁电池,电解液,Mg(AX4-nRn′R′n″)2络合物,熔盐,聚合物电解质

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Abstract:

由于金属镁具有能量密度较高、价格低、操作安全等优点,可充镁电池是在大负荷储能方面极具发展潜力的二次电池。本文综述了可充镁电池电解液的研究进展,其中包括溶于醚溶剂中的格氏试剂、Mg(BR2R′2)2(其中R、R′为烷基或芳基)、Mg(AX4-nRn′R′n″)2络合物(其中A=Al、B、Sb、P、As、Fe和Ta等,X=Cl、Br和F,R、R′为烷基或芳基,0

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