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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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改性石墨烯用作燃料电池阴极催化剂
DOI: 10.7536/PC121110, PP. 717-725
Keywords: 石墨烯改性,燃料电池,氧还原反应,阴极催化剂
Abstract:
石墨烯材料以其独特的超薄片层结构、超高比表面积、良好的导电性等重要特性,而被认为在制备高性能燃料电池催化剂方面具有重要的潜在应用价值。最近的一些研究工作表明,通过选择合适的制备方法和前驱体制备的改性石墨烯,对于氧还原反应具有一定的活性,可用作燃料电池阴极催化剂。目前有关石墨烯应用于燃料电池阴极催化剂的研究工作主要集中在两个方面一是通过表面改性后直接作为燃料电池非贵金属阴极催化剂;二是将改性石墨烯作阴极催化剂载体而制备活性组分高度分散的高性能催化剂。尽管有关改性石墨烯的氧还原活性中心的结构尚不明确,然而由于这类材料在酸性及碱性环境下对氧还原的良好的催化性能,对改性石墨烯的研究已成为探索燃料电池非铂催化剂的新途径。随着这类材料的催化性能的不断提高和对表面-活性关系认识的不断深入,改性石墨烯材料在燃料电池方面将具有广阔的应用前景。
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