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OALib Journal期刊
ISSN: 2333-9721
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水相中糖识别人工受体
DOI: 10.7536/PC130631, PP. 48-60
Keywords: 糖识别,人工受体,水相,非共价键相互作用,仿生
Abstract:
自然界中，糖类不仅作为生命体系的能量物质和结构物质，而且还作为信息分子在生命过程的细胞识别和调控中扮演着重要的角色，因此对糖识别的研究将极大地有助于糖类参与生理和病理过程的研究。生命体系中糖识别过程一方面基于受体的极性基团与糖羟基的氢键作用，另一方面依靠受体结构中的含芳环非极性基团与糖CH基相互作用，所以在极性溶液水中通过非共价键相互作用实现糖识别过程是当今化学界一个十分吸引人且又极具挑战性的研究课题。人工合成糖识别受体为研究自然界中糖识别过程的基本机制提供了一种有参考价值的模型系统，同时为仿生应用提供了有力的技术支持。本文从超分子化学、多分枝型、合成凝集素类和聚合物界面4种体系论述了近年来非硼酸类人工糖识别受体在水相中识别糖的研究进展及其潜在应用，并且对合成凝集素和界面糖识别体系做了特殊点评，最后对仿生人工合成受体在水相中对糖识别的未来的发展方向做了展望。
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