OALib Journal期刊
手性催化剂在不对称羰基ene反应中的应用
DOI: 10.7536/PC140319
Keywords: 手性高烯丙醇 ,羰基ene反应 ,不对称催化 ,手性有机金属催化剂 ,手性有机小分子催化剂
Abstract:
手性高烯丙基醇类化合物是一类非常重要的有机合成中间体，被广泛应用于药物分子和天然产物的合成中，不对称羰基ene反应是构建此类化合物最有效的方法之一，近年来已经取得了巨大进展。目前，在不对称羰基ene反应中的手性催化剂主要有如Mg、Ca、Sc、Ti、Co、Ni、Cu、Rh、Pd、Pt等金属与手性配体络合形成的配合物，以及一些手性有机小分子，大部分都取得了较好的催化活性与对映选择性。本文就此评述了各类手性催化剂在不对称羰基ene反应中的应用，不对称诱导反应的机理，以及催化剂分子结构及反应条件对催化活性和对映选择性的影响。
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